[Ru(η(6)-1,2,4,5-C6H2(CH3)4)Cl2(κ-(1)-P-(C6H5)2PCH2P(C6H5)2(=N-p-C5F4N))] | 514845-65-9

• 英文名称: [Ru(η(6)-1,2,4,5-C6H2(CH3)4)Cl2(κ-(1)-P-(C6H5)2PCH2P(C6H5)2(=N-p-C5F4N))]
• CAS: 514845-65-9
• 化学式: C₄₀H₃₆Cl₂F₄N₂P₂Ru
• 分子量: 854.656
• InChiKey: NUYSDTHANKVRKE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  silver hexafluoroantimonate 、 [Ru(η(6)-1,2,4,5-C6H2(CH3)4)Cl2(κ-(1)-P-(C6H5)2PCH2P(C6H5)2(=N-p-C5F4N))] 以 二氯甲烷 为溶剂， 以85%的产率得到[Ru(η(6)-1,2,4,5-C6H2(CH3)4)Cl2(κ-(2)-P,N-(C6H5)2PCH2P(C6H5)2(=N-p-C5F4N))][SbF6]
  参考文献：
  名称：

  Neutral and cationic (η6-arene)-ruthenium(II) complexes containing the iminophosphorane–phosphine ligand Ph2PCH2P(N-p-C5F4N)Ph2: influence of the arene ring in catalytic transfer hydrogenation of cyclohexanone

  摘要：

  Ruthenium(11) dimers [{Ru(eta(6)-arene)(mu-Cl)Cl}(2)] (la-f) readily react with the iminophosphorane-phosphine ligand Ph2PCH2P(= N-p-C5F4N)Ph-2 (2), in dichloromethane at room temperature, to afford the neutral derivatives [RU(eta(6)-arene)Cl-2{k(1)-P-Ph2PCH2P(N-p-C5F4N)Ph-2}] (arene=C6H6 (3a), 1-'Pr-4-C6H4Me (3b), l,3,5-C6H3Me3 (3c), l,2,3,4-C6H2Me4 (3d), 1,2,4,5-C6H2Me4 (3e), C6Me6 (3f)). Treatment of 3a-f with AgSbF6 in dichloromethane yields the cationic species [Ru(eta(6)-arene)Cl{k(2-)P,N-Ph2PCH2P( N-p-C5F4N)Ph-2}][SbF6] (4a-f). The catalytic activity of complexes 3 and 4 in transfer hydrogenation of cyclohexanone by propan-2-ol has been studied. Among them, the cationic derivative [Ru(eta(6)-C6Me6)Cl{k(2)-P,N-Ph2PCH2P(=N-p-C5F4N)Ph-2}][SbF6] (4f) shows the highest activity. Electrochemical data for 3 and 4 are also reported. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01641-8
• 作为产物：
  描述：

  [Ru(η(6)-durene)(μ-Cl)Cl]2 、 p-NC5F4NPPh2CH2PPh2 以 二氯甲烷 为溶剂， 以88%的产率得到[Ru(η(6)-1,2,4,5-C6H2(CH3)4)Cl2(κ-(1)-P-(C6H5)2PCH2P(C6H5)2(=N-p-C5F4N))]
  参考文献：
  名称：

  Neutral and cationic (η6-arene)-ruthenium(II) complexes containing the iminophosphorane–phosphine ligand Ph2PCH2P(N-p-C5F4N)Ph2: influence of the arene ring in catalytic transfer hydrogenation of cyclohexanone

  摘要：

  Ruthenium(11) dimers [{Ru(eta(6)-arene)(mu-Cl)Cl}(2)] (la-f) readily react with the iminophosphorane-phosphine ligand Ph2PCH2P(= N-p-C5F4N)Ph-2 (2), in dichloromethane at room temperature, to afford the neutral derivatives [RU(eta(6)-arene)Cl-2{k(1)-P-Ph2PCH2P(N-p-C5F4N)Ph-2}] (arene=C6H6 (3a), 1-'Pr-4-C6H4Me (3b), l,3,5-C6H3Me3 (3c), l,2,3,4-C6H2Me4 (3d), 1,2,4,5-C6H2Me4 (3e), C6Me6 (3f)). Treatment of 3a-f with AgSbF6 in dichloromethane yields the cationic species [Ru(eta(6)-arene)Cl{k(2-)P,N-Ph2PCH2P( N-p-C5F4N)Ph-2}][SbF6] (4a-f). The catalytic activity of complexes 3 and 4 in transfer hydrogenation of cyclohexanone by propan-2-ol has been studied. Among them, the cationic derivative [Ru(eta(6)-C6Me6)Cl{k(2)-P,N-Ph2PCH2P(=N-p-C5F4N)Ph-2}][SbF6] (4f) shows the highest activity. Electrochemical data for 3 and 4 are also reported. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01641-8