[NiP(4-CH3-C6H4)3]2[μ-(η-CH2CHCH3Si(μ-NH))4] | 467435-00-3

• 英文名称: [NiP(4-CH3-C6H4)3]2[μ-(η-CH2CHCH3Si(μ-NH))4]
• CAS: 467435-00-3
• 化学式: C₅₄H₇₀N₄Ni₂P₂Si₄
• 分子量: 1066.85
• InChiKey: RPFUGRYMRGVKAM-SXDRHABGSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  bis(1,5-cyclooctadiene)nickel (0) 、 1,3,5,7-四甲基-1,3,5,7-四乙烯基环四硅氮烷 、 三对苯甲基膦 以 乙醚 为溶剂， 生成 [NiP(4-CH3-C6H4)3]2[μ-(η-CH2CHCH3Si(μ-NH))4]
  参考文献：
  名称：

  Phosphine nickel(0) π-complexes with vinylcyclosilazane—synthesis and structure

  摘要：

  Synthesis, spectroscopic (H-1, C-13, P-31, Si-29 NMR) characterisation and X-ray structure of the first nickel(0) pi-complex with vinylcyclosilazane [{Ni(PPh3)}(2){mu-(eta-CH2=CH(Me)Si(mu-NH))(4)}] (1a) have been presented. This is the first report on the structure of a TM complex with a vinylsilazane ligand. Complex la is synthesised by the reaction of [Ni(cod)(2)] with cyclotetra (vinylmethylsilazane). The complex occupies a special position of the space group P2(1)/c on the centre of symmetry that lies in the middle of the cyclotetrasilazane ring. The coordination of nickel is close to triangular one. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(02)01001-x