[Ga(N(SP(i-Pr)2)(SeP(i-Pr)2)-S,Se)2][GaCl4] | 860473-10-5

• 英文名称: [Ga(N(SP(i-Pr)2)(SeP(i-Pr)2)-S,Se)2][GaCl4]
• CAS: 860473-10-5
• 化学式: C₂₄H₅₆GaN₂P₄S₂Se₂*Cl₄Ga
• 分子量: 999.927
• InChiKey: JNTWNIDEBWYERY-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  i-Pr2P(S)NHP(Se)-i-Pr2 在 n-BuLi 作用下， 以 正己烷 、 甲苯 、 苯 为溶剂， 生成 [Ga(N(SP(i-Pr)2)(SeP(i-Pr)2)-S,Se)2][GaCl4]
  参考文献：
  名称：

  Synthesis and structural characterization of gallium and indium complexes obtained from redistribution reactions of mixed chalcogen-imidodiphosphinate ligands

  摘要：

  The ionic complex [Ga{N(SP'Pr-2)(SeP'Pr-2)-S, Se}(2)](+)[GaCl4](-) (5) was prepared by a ligand redistribution process from the monochelate Cl2Ga{N(SP'Pr-2)(SeP'Pr-2)-S,Se}] (3) complex in benzene. A similar phenomenon was observed for the heavier indium homologues, where the neutral complexes [ClIn{N(SP'Pr-2)(SeP'Pr-2)-S, Se}(2)] (7) and [ClIn{N(OP'Pr-2)(SP'Pr-2)-O, S}(2)] (8) were isolated along with InCl3 as the main reaction by-product. Complexes 5, 7 and 8 were characterized by single-crystal X-ray structural analysis. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.03.042