[CpMoCl2]2 | 131856-29-6

• 英文名称: [CpMoCl2]2
• CAS: 131856-29-6
• 化学式: C₁₀H₁₀Cl₄Mo₂
• 分子量: 463.881
• InChiKey: LMMYSPTZDTZVDK-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [CpMoCl2]2 、 (S,S)-N.N'-ethanediylidene-bis(α-methylbenzenemethylamine) 以 甲苯 为溶剂， 以65%的产率得到
  参考文献：
  名称：

  Half-sandwich Mo(III) complexes with asymmetric diazadiene ligands

  摘要：

  The asymmetric 1,4-diazadiene ligands (RN)-N-*=CHCH=NR* [R-* = (S)-CH(CH3)Ph], R(2)(*)dad, and 2,2'-bis(4-ethyloxazoline), as-ox, have been used to generate half-sandwich Mo-111 derivatives by addition to CP2Mo2Cl4. Ligand R(2)(*)dad affords a mononuclear, paramagnetic 17-electron product, CpMoCl2(R(2)(*)dad), whereas as-ox leads to the isolation of a dinuclear compound where only one molecule of ligand has been added per two Mo atoms, Cp2Mo2Cl4(as-ox). In the presence of free as-ox, this compound coexists with the paramagnetic mononuclear complex in solution. Both products are capable of controlling the radical polymerization of styrene under typical atom transfer radical polymerization (ATRP) conditions. However, the tacticity of the resulting polystyrene does not differ from that given by conventional free radical polymerization. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.04.013

文献信息

• Four-Legged Piano Stool Molybdenum(II) Compounds without Carbonyl Ligands. 4. Cyclopentadienylmolybdenum(II) Complexes with 16-Electron and 18-Electron Configurations
  作者：Fatima Abugideiri、James C. Fettinger、D. Webster Keogh、Rinaldo Poli

  DOI：10.1021/om960331d

  日期：1996.10.15

  analysis, and X-ray structural determination. Thermolysis of a THF or C6D6 solution of this 18-electron species generates the 16-electron paramagnetic Mo(II) complex CpMoCl(PMe2Ph)2. The Cp*MoClL2 (L = PMe3 and PMe2Ph) systems react with 2-electron-donor ligands, i.e. CO and H2, to afford stable 18-electron complexes. The carbonyl derivative Cp*MoCl(CO)(PMe2Ph)2 has also been characterized by X-ray crystallography

  具有（Ring）MoClL x形式的16和18电子构型的Mo（II）的单环戊二烯基络合物x（x = 2，Ring = Cp，L = PMe 2 Ph; x = 2，Ring = Cp *，L = PMe参照图3，描述了PMe 2 Ph，L 2＝ dppe；x＝ 3，Ring ＝ Cp，L ＝ PMe 2 Ph。如固态和溶液中的磁测量以及接触位移的1 H NMR光谱所示，所有16电子配合物都是S = 1基态的顺磁性。通过X射线衍射法确定Cp * MoCl（dppe）的结构。18电子络合物CPMoCl（PMe 2 Ph）3已被还原的CPMoCl合成2 } Ñ用Na在3当量膦的存在下进行。它的特征在于1 H和31 P NMR，化学分析和X射线结构测定。此18电子物种的THF或C 6 D 6溶液的热解生成16电子顺磁性Mo（II）络合物CPMoCl（PMe 2 Ph）2。Cp * MoClL 2（L