[(η5-C5Me5CHMe2)2TiCl] | 808132-87-8

• 英文名称: [(η5-C5Me5CHMe2)2TiCl]
• CAS: 808132-87-8
• 化学式: C₂₄H₃₈ClTi
• 分子量: 409.899
• InChiKey: QBKLSVZUZUZHIV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(η5-C5Me5CHMe2)2TiCl] 在 sodium amalgam 作用下， 以 not given 为溶剂， 生成 (η5-C5Me4CHMe2)2Ti
  参考文献：
  名称：

  Dinitrogen Activation by Titanium Sandwich Complexes

  摘要：

  The activation of dinitrogen by titanium sandwich complexes of the general form (eta5-C5Me4R)2Ti (R = CHMe2, CMe3, SiMe3) has been systematically investigated. Low-temperature, in situ, solution infrared spectroscopy has allowed detection of monomeric bis-dinitrogen complexes of titanium that are isostructural with more familiar dicarbonyl derivatives. One example, (eta5-C5Me4CHMe2)2Ti(N2)2, has also been characterized by X-ray diffraction and reveals weakly activated dinitrogen ligands. From the solution IR data, the relative azophilicity of the titanium sandwich complexes has been established and increases with smaller cyclopentadienyl substituents.

  DOI：

  10.1021/ja045884r