[Ag(γ-terpinene)2]PF6 | 892392-54-0

• 英文名称: [Ag(γ-terpinene)2]PF6
• CAS: 892392-54-0
• 化学式: C₂₀H₃₂Ag*F₆P
• 分子量: 525.306
• InChiKey: URJAYGXXZBGHMR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  六氟磷酸银 、 γ-松油烯 以 二氯甲烷 为溶剂， 生成 [Ag(γ-terpinene)2]PF6
  参考文献：
  名称：

  X-ray crystal structures of discrete and polymeric chiral silver complexes of monoterpenoid alkenes

  摘要：

  X-ray crystal structures are reported for five silver(l) complexes of four monoterpenoid alkenes. Discrete mononuclear complexes of the chiral alkenes (1S)-(-)-alpha-pinene and (1S)-(-)-beta-pinene with silver perchlorate and silver hexafluorophosphate are described. The achiral diene gamma-terpinene forms a discrete mononuclear adduct with silver hexafluorophosphate and a two-dimensional polymeric network structure with silver triflate. The chiral diene (R)-(+)-limonene forms a one-dimensional chiral coordination polymer with silver hexafluorophosphate. In all structures the silver atom is eta(2)-bonded to the carbon-carbon bond(s) of the monoterpene with slightly longer bond distances to the more substituted carbon of the alkene moiety. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.11.046