| 914616-88-9

• CAS: 914616-88-9
• 化学式: C₂₂H₂₆Cl₂CoN₂O₂
• 分子量: 480.36
• InChiKey: HGFUWCWFSMLODW-NASQSZSQSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 在 RuCl2(1,3-dimesityl-imidazolidin-2-yl)(PCy3)(=CHPh) 作用下， 以 二氯甲烷 为溶剂， 以63%的产率得到
  参考文献：
  名称：

  Early–late heterobimetallic complexes as initiator for ethylene polymerization. Cooperative effect of two metal centers to afford highly branched polyethylene

  摘要：

  由早过渡金属配合物引发的乙烯聚合提供了具有不同支化结构和性能的聚合物，具体取决于后过渡金属的类型。

  DOI：

  10.1039/b605800k
• 作为产物：
  描述：

  cobalt(II) chloride 、 [6-[[2,6-Di(propan-2-yl)phenyl]iminomethyl]pyridin-2-yl]methyl prop-2-enoate 生成
  参考文献：
  名称：

  Structures of Co, Pd and Ni complexes with iminopyridine ligands having an hydroxymethyl or acrylate pendant group

  摘要：

  Co(II), Pd(II) and Ni(II) complexes with iminopyridine ligands have different coordination structures in the solid state, depending on the metal, pendant group of the pyridyl ring and recrystallization conditions. The iminopyridine ligand having an acrylate group, Ar-N=CH-2,6-C5H3N-CH2-OCO-CH=CH2 (L-1: At = 2,6-diisopropylphenyl), forms a Co(II) complex whose metal center has a trigonal pyramidal coordination with two chloride ligands and an N,N'-bidentate ligand L-1. Both L-1 and the iminopyridine ligand with a CH2OH pendant on the pyridyl ring, Ar-N=CH-2,6-C5H3N-CH2-OH (L-2: Ar = 2,6-diisopropylphenyl), coordinate to the PdCl2 moiety, giving complexes with a square-planar coordination. The reaction of L-1 with [NiBr2(H2O)(3)] and recrystallization of the products forms crystals which contain mono- and dinuclear complexes with aqua ligands and the N,N'-bidentate ligand. L-2 is coordinated to the Ni(II) center as an N,N',O-tridentate ligand. Recrystallization of the products of the reaction of L-2 with [NiBr2(H2O)(3)] with and without excess H2O in the solution yields crystals of the cationic octahedral complex with two aqua ligands [NiBr(H2O)(2)(L-2)]Br and the neutral square pyramidal complex [NiBr2(L-2)], respectively. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.04.050