| 201555-24-0

• CAS: 201555-24-0
• 化学式: BF₄*C₂₆H₅₀P₂Rh
• 分子量: 614.341
• InChiKey: QGZSWTULXSVXTH-XDWRCRRRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  bis(ethylene)rhodium(I) chloride dimer 、 2,5-降冰片二烯 、 1，3-双（二叔丁基膦）丙烷 、 silver tetrafluoroborate 以 二氯甲烷 为溶剂， 生成 、
  参考文献：
  名称：

  Synthesis and X-ray crystal structures of tetraalkyl diphosphine complexes of silver(I), [Ag2 {Bu2tP(CH2)3PBi2t}2][BF4]2 · 2 CH2Cl2 and [Ag2 {Bu2tP(CH2)2PBu2t}(H2O)2][BF4]2

  摘要：

  The title complexes [Ag-2(dbpp)(2)](BF4)(2) (1) and [Ag-2(dbpe)(H2O)(2)](BF4)(2) (2), obtained as unexpected by-products while using AgBF4 to eliminate Cl- from rhodium complexes, were isolated and characterised by single-crystal X-ray diffraction. 1 was also prepared directly. The Ag atoms are bridged by two (1) or one (2) diphosphine ligands and have a linear P, P or P, H2O coordination. According to the P-31{H-1} spectra, the cation of 1 retains this structure in solution. Weak Ag ... F interactions with anions (in 2 'supported' by OH ... F hydrogen bonds) form two additional interaction bridges in 1 or link the Ag atoms in a catena-fashion in 2 and complement the Ag-I coordination to a trigonal-bipyramidal arrangement(with one equatorial site void). (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(97)00294-5