H2Os3(CO)10(NH2Et) | 196940-09-7

• 英文名称: H2Os3(CO)10(NH2Et)
• CAS: 196940-09-7
• 化学式: C₁₂H₉NO₁₀Os₃
• 分子量: 897.804
• InChiKey: XHSBUKAGYKKRNA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  Os3(μ-H)2(CO)10 、 乙胺 生成 H2Os3(CO)10(NH2Et)
  参考文献：
  名称：

  Role of Os−H- - -H−N Interactions in Directing the Stereochemistry of Carbonyl Cluster Hydride Derivatives

  摘要：

  Unconventional hydrogen-bond interactions involving metal hydrides as proton acceptors from N-H bonds have been recently discovered in mononuclear organometallic systems. The work herein reported on H2Os3(CO)(10)L (L= NH2Et, NHEt2) suggests that this type of interaction may be even more important in cluster chemistry in directing the stereochemistry of the products as well as affecting the intramolecular ligand exchange processes.

  DOI：

  10.1021/om9706370