mer-trans-bromo(methyl)-(1-carbonyl-2-oxo-1,2-diphenyl-diyl)bis(trimethylphosphine)nickel | 260997-75-9

• 英文名称: mer-trans-bromo(methyl)-(1-carbonyl-2-oxo-1,2-diphenyl-diyl)bis(trimethylphosphine)nickel
• CAS: 260997-75-9
• 化学式: C₂₂H₃₁BrNiO₂P₂
• 分子量: 528.028
• InChiKey: SRBYAKPHYPXLPJ-HXTYYFCZSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  、 mer-trans-bromo(methyl)-(1-carbonyl-2-oxo-1,2-diphenyl-diyl)bis(trimethylphosphine)nickel 以 乙醚 为溶剂， 以29%的产率得到[(1,2-diphenyl-2-oxo-ethene-1-yl)carbonyl]tris(trimethylphosphine)nickel
  参考文献：
  名称：

  Oxidation–reduction exchange of 2-acylenolato and trimethylphosphane ligands between d6 and d8 complexes of nickel and cobalt

  摘要：

  A series of five (C:O)-dianionic 1-acyl-2-enolato ligands C(O)-C=C-O in a transmetallation reaction between 18-electron metal-d(6) complexes mer-trans-NiMe(X)[C(O)-C=C-O](PMe3)(2) [C=C=C6H4, X = I (1); C=C=3-CMe3-5-Me-C6H2, X=I (2); C=C=5,6-benzo-C6H2, X = I (3); C=C=3,4-benzo-cyclohexene, X = Br (4); C=C=1,2-diphenylethene, X = I (5)] and the 18-electron metal-d(8) compound CoMe(PMe3)(4) (1:2), undergo a reductive coupling of acyl and methylnickel functions involving the C(O)-C=C-O ligands. Subsequent migration of methyl groups between cobalt intermediates generates three products: mer-trans-CoMe2[MeC(O)-C=C-O](PMe3)(2) (6-10), Ni(PMe3)(4), and CoX(PMe3)(3). The X-ray crystal structure of compound 7 has been determined. The methyl ligands are found in positions opposite to the O-donor functions. Upon replacing the aromatic rings in salicylaldehyde derivatives C(O)-C=C-O by more flexible cyclohexene rings or acyclic systems the reduction of Ni(IV) complexes follows a different course. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00331-x
• 作为产物：
  描述：

  溴甲烷 、 [(1,2-diphenyl-2-oxo-ethene-1-yl)carbonyl]tris(trimethylphosphine)nickel 以 乙腈 为溶剂， 以89%的产率得到mer-trans-bromo(methyl)-(1-carbonyl-2-oxo-1,2-diphenyl-diyl)bis(trimethylphosphine)nickel
  参考文献：
  名称：

  Oxidation–reduction exchange of 2-acylenolato and trimethylphosphane ligands between d6 and d8 complexes of nickel and cobalt

  摘要：

  A series of five (C:O)-dianionic 1-acyl-2-enolato ligands C(O)-C=C-O in a transmetallation reaction between 18-electron metal-d(6) complexes mer-trans-NiMe(X)[C(O)-C=C-O](PMe3)(2) [C=C=C6H4, X = I (1); C=C=3-CMe3-5-Me-C6H2, X=I (2); C=C=5,6-benzo-C6H2, X = I (3); C=C=3,4-benzo-cyclohexene, X = Br (4); C=C=1,2-diphenylethene, X = I (5)] and the 18-electron metal-d(8) compound CoMe(PMe3)(4) (1:2), undergo a reductive coupling of acyl and methylnickel functions involving the C(O)-C=C-O ligands. Subsequent migration of methyl groups between cobalt intermediates generates three products: mer-trans-CoMe2[MeC(O)-C=C-O](PMe3)(2) (6-10), Ni(PMe3)(4), and CoX(PMe3)(3). The X-ray crystal structure of compound 7 has been determined. The methyl ligands are found in positions opposite to the O-donor functions. Upon replacing the aromatic rings in salicylaldehyde derivatives C(O)-C=C-O by more flexible cyclohexene rings or acyclic systems the reduction of Ni(IV) complexes follows a different course. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00331-x