| 219974-11-5

• CAS: 219974-11-5
• 化学式: C₁₅H₃₆BaMo₂O₁₅
• 分子量: 785.652
• InChiKey: IGMVRHTYPGGGBI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 乙二醇甲醚 、 barium 以 neat (no solvent) 为溶剂， 生成
  参考文献：
  名称：

  Synthesis, crystal and molecular structure of a new heterometallic oxo-2-methoxyethoxide, BaMo2O5(OC2H4OMe)4(HOC2H4OMe)

  摘要：

  The colorless needle-shaped crystals of a new heterometallic 2-methoxyethoxide, BaMo2O5(OC2H-4OMe)(4)(HOC2H4OMe) (1), have been obtained by the saturation of barium 2-methoxyethoxide solution in 2-methoxyethanol with the crystalline MoO2(OC24H,OMe)(2). The precipitation started when the Ba:Mo ratio achieved a 1:2 value and the precipitate formed contained BaMoO4 as an admixture thus indicating that the formation of oxo species led partially even to formation of inorganic molybdates. Molecules of 1 involve the metal-oxygen framework quite typical of trinuclear homo- and heterometallic alkoxide species. The rather high coordination number of the barium atom (10) and the lengths of the observed interatomic distances permit to suggest that this atom in 1 forms predominantly ionic bonds and, therefore, complex 1 can be formulated as [Ba(HOC2H4OMe)](2+) [Mo2O5(OC2H4OMe)(4)](2-). (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00227-7