(hydroxy-d)zinc | 135659-06-2

• 英文名称: (hydroxy-d)zinc
• CAS: 135659-06-2
• 化学式: HOZn
• 分子量: 83.3894
• InChiKey: YVZATJAPAZIWIL-DYCDLGHISA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.56
• 重原子数：
  2.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  20.23
• 氢给体数：
  1.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  以 solid matrix 为溶剂， 生成 (hydroxy-d)zinc
  参考文献：
  名称：

  在15 K下研究原子和双原子铬，锰，铁，钴，镍，铜和锌与分子水的反应

  摘要：

  DOI：

  10.1021/j100262a023

文献信息

• Gas-Phase Synthesis and Structure of Monomeric ZnOH: A Model Species for Metalloenzymes and Catalytic Surfaces
  作者：Lindsay N. Zack、Ming Sun、Matthew P. Bucchino、Dennis J. Clouthier、Lucy M. Ziurys

  DOI：10.1021/jp209875a

  日期：2012.2.16

  Monomeric ZnOH has been studied for the first time using millimeter and microwave gas-phase spectroscopy. ZnOH is important in surface processes and at the active site of the enzyme carbonic anhydrase. In the millimeter-wave direct-absorption experiments, ZnOH was synthesized by reacting zinc vapor, produced in a Broida-type oven, with water. In the Fourier-transform microwave measurements, ZnOH was produced in a supersonic jet expansion of CH3OH and zinc vapor, created by laser ablation. Multiple rotational transitions of six ZnOH isotopologues in their X(2)A' ground states were measured over the frequency range of 22-482 GHz, and splittings due to fine and hyperfine structure were resolved. An asymmetric top pattern was observed in the spectra, showing that ZnOH is bent, indicative of covalent bonding. From these data, spectroscopic constants and an accurate structure were determined. The Zn-O bond length was found to be similar to that in carbonic anhydrase and other model enzyme systems.