Novel Metalloreagent Cp(CO)<sub>2</sub>FeP(Se)(OR)<sub>2</sub> Produced from P−Se Bond Cleavage in the Thermal Reaction of [CpFe(CO)<sub>2</sub>]<sub>2</sub> with Phosphor-1,1-diselenolates
作者:C. W. Liu、Jem-Min Chen、Bidyut Kumar Santra、Sung-Yin Wen、Ben-Jie Liaw、Ju-Chun Wang
DOI:10.1021/ic061538u
日期:2006.10.30
The reaction of [ CpFe( CO)(2)](2) with NH4Se2P( OR)(2) yields a novel reagent Cp( CO)(2)FeP( Se)( OR)(2), which has demonstrated coordination properties at the Se center to form heterometallic clusters as well as reactivity at the Se site toward C-based electrophiles.