cis-[RhCl(CO)2(N(COPh)C5H4CH2Ph)] | 1338493-83-6

• 英文名称: cis-[RhCl(CO)2(N(COPh)C5H4CH2Ph)]
• CAS: 1338493-83-6
• 化学式: C₂₁H₁₆ClN₂O₃Rh
• 分子量: 482.728
• InChiKey: UVLODFQTWASSDA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  N-(1-benzylpyridin-4(1H)-ylidene)benzamide 、 di(rhodium)tetracarbonyl dichloride 以 not given 为溶剂， 生成 cis-[RhCl(CO)2(N(COPh)C5H4CH2Ph)]
  参考文献：
  名称：

  Extending the Range of Neutral N-Donor Ligands Available for Metal Catalysts: N-[1-Alkylpyridin-4(1H)-ylidene]amides in Palladium-Catalyzed Cross-Coupling Reactions

  摘要：

  N[1-Alkylpyridin-4(1H)-yliden]amides (PYAs) are a new class of easily prepared, neutral N-donor ligands that share some features in common with N-heterocyclic carbenes. They are strongly electron-donating toward metal centers, and a palladium(II) complex of one of these ligands has been shown to successfully catalyze both the Heck-Mizoroki and Suzuki-Miyaura cross-coupling reactions.

  DOI：

  10.1021/ic201527s