bis(μ-chloro)bis(4-heptoxy-4'-fluoroazobenzenyl)dipalladium | 1286673-59-3

• 英文名称: bis(μ-chloro)bis(4-heptoxy-4'-fluoroazobenzenyl)dipalladium
• CAS: 1286673-59-3
• 化学式: C₃₈H₄₄Cl₂F₂N₄O₂Pd₂
• 分子量: 910.536
• InChiKey: PVHCAVZEBYIZDB-RUZCOOILSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二(氰基苯)二氯化钯 、 4-heptoxy-4'-fluoroazobenzene 以 乙醇 为溶剂， 生成 bis(μ-chloro)bis(4-heptoxy-4'-fluoroazobenzenyl)dipalladium 、 bis(μ-chloro)bis(4-heptoxy-4'-fluoroazobenzenyl)dipalladium
  参考文献：
  名称：

  Syntheses, Electronic Structures, and Dichroic Behavior of Dinuclear Cyclopalladated Complexes of Push−Pull Azobenzenes

  摘要：

  Eight new chloride-/acetate-bridged dimeric Pd-II complexes have been synthesized by using 4-heptoxyazobenzenes 4'-substituted with groups of varying electron-withdrawing strength (NO2, CN, F, or CO2Et). The effects of charge density distribution and the bridging ligand on the relative proportions of structural and geometrical isomers produced is explored by using NMR spectroscopy. UV-vis spectroscopy reveals a single low-energy absorption for each proligand but three distinct bands for each of the complexes. The origins of the observed absorptions are inferred from the effects of changing the bridging ligands and corroborated by time-dependent density functional theory (TD-DFT) calculations. Dichroic ratio (DR) measurements in two different liquid-crystal (LC.) hosts show decreased performance upon complexation, although the results are notably wavelength dependent. The lowest energy absorption band, associated with intraligand charge-transfer transitions, displays superior dichroism with respect to the adjacent band at higher energy. The transition dipole moment directions calculated via TD-DFT correlate with the observed DR results, implying a decrease in alignment within the LC hosts for the complexes with respect to their proligands.

  DOI：

  10.1021/om101189f