trans-[bis(dimethylglyoximate)(triphenylphosphine)chlororhodium(III)] | 31249-66-8

• 英文名称: trans-[bis(dimethylglyoximate)(triphenylphosphine)chlororhodium(III)]
• CAS: 31249-66-8
• 化学式: C₂₆H₂₉ClN₄O₄PRh
• 分子量: 630.873
• InChiKey: QZFTWHBRUXOCES-DVTASQICSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  trans-[bis(dimethylglyoximate)(triphenylphosphine)chlororhodium(III)] 在 H₂O 作用下， 以 甲醇 、 水 为溶剂， 生成
  参考文献：
  名称：

  Dreos Garlatti, R.; Tauzher, G.; Costa, G., Inorganica Chimica Acta, 1986, vol. 121, p. 27 - 32

  摘要：

  DOI：

文献信息

• Synthetic routes and structures of [Rh(Hdmg){ClZn(C2H5OH)dmg}(PPh3)Cl], [Rh(Hdmg)2(PPh)2]+[Rh(Hdmg)2(Cl)2]−·2CH3OH, and [Rh(Hdmg)2(PPh3)I]·0.5C2H5OH complexes
  作者：Monika Moszner、Zbigniew Ciunik、Józef J. Ziółkowski

  DOI：10.1016/s0277-5387(03)00468-6

  日期：2003.11

  Treatment of [Rh(Hdmg)(2)(PPh3)Cl] with zinc amalgam afforded a heterobimetallic compound [Rh(Hdmg)(ClZndmg)(PPh3)Cl] (1a) (Hdmg=monoanion of dimethylglyoxime). Crystallization of (la) from a CHCl3/C2H5OH mixture led to the formation of [Rh(Hdmg)ClZn(C2H5OH)dmg)(PPh3)Cl] (1). The X-ray crystal structure of 1 revealed that the ethanol molecule was built into the complex molecule through the oxygen atom coordinated to the zinc cation and a hydrogen bond involving one of the chloride ligands. Reduction of [Rh(Hdmg)(2)(PPh3)Cl] with Zn/Hg, followed by treatment with a CHCl3/CH3OH mixture, gave the complex salt [Rh(Hdmg)(2)(PPh3)(2)](+)[Rh(Hdmg)(2)(Cl)(2)](-) . 2CH(3)OH (2). The X-ray structure of 2 showed crystals formed by cations [Rh(Hdmg)(2)(PPh3)(2)](+) and anions [Rh(Hdmg)(2)Cl-2](-). The anion binds one CH3OH molecule through a hydrogen bond involving the adjacent oxime atom. Reduction of [Rh(Hdmg)(2)(PPh3)Cl] with zinc amalgam in the presence of CH3I led to the compound [Rh(Hdmg)(2)(PPh3)I] . 0.5C(2)H(5)OH (3), which was characterized by X-ray crystallography. (C) 2003 Elsevier Ltd. All rights reserved.
• An unusual selective reduction of an oxime into an imine group in halogenomethyl rhodoximes
  作者：Dirk Steinborn、Mario Rausch、Clemens Bruhn

  DOI：10.1016/s0022-328x(98)00534-8

  日期：1998.6

  [Rh(dmgH)(2)(PPh3)](-) ([Rh](-), 1) [Rh] = [Rh(dmgH)(2)(PPh3)]; (dmgH)(2) = dimethylglyoxime}, obtained by reduction of [Rh]-Cl with NaBH4 in methanolic KOH, reacts with dihalogenomethanes CH2X2 (X = Br, Cl) to give besides the known complexes [Rh]-CH2X (X = Br, 2a; X = Cl, 2b) the complexes [Rh(CH2X) ON=C(Me)-C(Me)=NH}(dmgH)(PPh3)] (X = Br, 3a; X = Cl, 3b) where one oxime unit is reduced to an imine. Due to the strong alkaline medium (methanolic KOH) 3a was found to react partially, yielding [Rh(CH2OMe) ON=C(Me)-C(Me)=NH} (dmgH)(PPh3)] (3c). All three complexes were characterized by H-1-, C-13-, P-31-NMR spectroscopy. 3a crystallizes in the triclinic space group P (1) over bar with two molecules in the asymmetric unit. These molecules are linked via two N-H ... O hydrogen bridges forming a dimer. The rhodium atoms display a distorted octahedral coordination with the dmgH/ON=C(Me)-C(Me)=NH ligands in the equatorial plane and PPh3 and the CH2Br ligands in the axial positions. (C) 1998 Elsevier Science S.A. All rights reserved.