[Pd(N,N-dimethylbenzylamine)(1,3,5-C6H2(CF3)3)(CO)] | 460312-21-4

• 英文名称: [Pd(N,N-dimethylbenzylamine)(1,3,5-C6H2(CF3)3)(CO)]
• CAS: 460312-21-4
• 化学式: C₁₉H₁₄F₉NOPd
• 分子量: 549.732
• InChiKey: ZRDMEPXKRVHIJG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2,4,6-tris(trilfuoromethyl)phenyllithium 以 乙醚 、 甲苯 为溶剂， 生成 [Pd(N,N-dimethylbenzylamine)(1,3,5-C6H2(CF3)3)(CO)]
  参考文献：
  名称：

  Neutral Organometallic Palladium(II) Aquo Complexes

  摘要：

  The reactions of chlorobridged cyclometalated complexes [Pd(C-N)(mu-Cl)](2) (C-N = orthometalated N,N-dimethylbenzylamine, dmba; 2-(para-tolyl)pyridine, p-tolpy; azobenzene, azb; N,N-dimethyl-1-naphthylamine, dmna; and 2-benzylpyridine, bzpy) with Li(Fmes) (Fimes = 2,4,6-tris(trifluoromethyl)phenyl or nonafluoromesityl) give, after hydrolysis, neutral aquo complexes [Pd(C-N)(Fmes)(OH2)] where the ipso carbon atoms of the Fines and the cyclometalated ligand are coordinated cis, as shown by an X-ray diffraction study of [Pd(dmba)(Fmes)(OH2)]. The aquo ligand is readily displaced by other ligands, giving complexes [Pd(C-N)(Fmes)L] (1, = PPh3, 2,6-lutidine, NH3, (CNBu)-Bu-t, CO) when monodentate ligands are employed or [Pd(dmba-C)(Fmes)(2,2'-bipy)], which contains a chelating 2,2'-bipyridyl and a monodentate C-bonded dmba, Different processes in solution are detected for the complexes containing the bulkier ligands: ligand rotation in the complex with PPh3; inversion of the bipy ligand in [Pd(dmba-C(Fmes)(2,2'-bipy)1; and equilibria with residual water in the solutions of [Pd(C-N)(Fmes)(lut)1 and [Pd(dmba-C)(Fmes)(2,2-bipy)].

  DOI：

  10.1021/om020198r