NiCl2(Hpao)2 | 1151540-32-7

• 英文名称: NiCl2(Hpao)2
• 英文别名: [Ni(pyridine-2-aldoxime)2Cl2]
• CAS: 1151540-32-7；16126-85-5；116908-53-3
• 化学式: C₁₂H₁₂Cl₂N₄NiO₂
• 分子量: 373.849
• InChiKey: YLXAREKXLZAYHX-LPJLZGJRSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  2,2'-联吡啶 、 NiCl2(Hpao)2 在 NaOH 作用下， 以 甲醇 为溶剂， 以71%的产率得到Ni(pyridine-2-aldoximate)2(2,2'-bipyridine)*2H2O
  参考文献：
  名称：

  Racemic nickel(II) pyridine-2-aldoximate complexes capped by 2,2′-bipyridine and 1,10-phenanthroline: syntheses, structures and magnetic properties

  摘要：

  Two Ni(II) pyridine-2-aldoximate complexes, Ni(pao)(2)(bpy) (1) and Ni(pao)(2)(phen) (2) (pao(-)pyridine-2-aldoximate, bpy = 2,2'-bipyridine, phen = 1,10-phenanthroline), were synthesized via the deprotonation of NiCl2(Hpao)(2) in methanol followed by the addition of bidentate ligands of 2,2'-bipyridine and 1,10-phenanthroline. Crystallization in CHCl3 gave block-type crystals of 1 and 2 in high yields. The mononuclear structure surrounded by three bidentate ligands, i.e., two pao(-) and one bpy or phen, was revealed by X-ray crystallography: 1 crystallizes in monoclinic space group P2(1)/c with cell dimensions of a = 13.457(3) Angstrom, b = 14.493(3) Angstrom, c = 19.104(4) Angstrom, beta = 108.681(3)degrees, Z = 4, and 2 crystallizes in monoclinic space group P2(1)/n with cell dimensions of a = 14.235(5) Angstrom, b = 12.018(4) Angstrom, c = 20.696(7) Angstrom, beta = 110.304(4)degrees, Z = 4.1 and 2 each have two oximate groups (pao(-)), with an NO-trans arrangement around the Ni-II ion. Complexes 1 and 2 are racemic, namely, each molecule has a chiral center of Delta or Lambda, thereby forming NO-trans-Delta and -Lambda geometries in the solid state. Magnetic measurements revealed a paramagnetic S = 1 spin state with a positive zero-field splitting parameter. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.11.029
• 作为产物：
  描述：

  2-吡啶甲醛肟 、 nickel(II) chloride hexahydrate 以 甲醇 为溶剂， 以90%的产率得到NiCl2(Hpao)2
  参考文献：
  名称：

  Selective Ethylene Oligomerization with Nickel Oxime Complexes

  摘要：

  Two nickel-oxime complexes, Ni (2-pyridine aldoxime)2 dichloride (6) and Ni (methyl 2-pyridyl ketone oxime)2 dichloride (7), were prepared and characterized by X-ray crystallography. Both complexes are six-coordinate and have 2-pyridylimines as ligand backbones, where the two nitrogen atoms from each of the oxime ligands coordinate to the metal, but the oxygen atom remains protonated and does not participate in bonding to the metal center. The complexes were found to be selective ethylene dimerization catalysts in the presence of cocatalyst such as methylaluminoxane (MAO) or diethyl aluminum chloride (DEAC). With DEAC, the productivity is considerably higher than with MAO. Under optimum conditions the productivity values are as high as 200 kg/mol catalyst/h/bar (for 6) to 335 kg/mol catalyst/h/bar (for 7). The selectivities toward dimerization under these conditions are 84% and 77%, respectively, with the terminal isomer 1-butene being the only (>= 99.5%) C4 product.

  DOI：

  10.1021/om900080h

文献信息

• Syntheses, Structures, and Magnetic Properties of a Family of Tetra-, Hexa-, and Nonanuclear Mn/Ni Heterometallic Clusters
  作者：Hui Chen、Cheng-Bing Ma、Da-Qiang Yuan、Ming-Qiang Hu、Hui-Min Wen、Qiu-Tian Liu、Chang-Neng Chen

  DOI：10.1021/ic201403k

  日期：2011.10.17

  A family of Mn-III/Ni-II heterometallic clusters, [(Mn4Ni5II)-Ni-III(OH)(4)(hmcH)(4)(pao)(8)Cl-2]center dot 5DMF (1 center dot 5DMF), [(Mn3Ni6II)-Ni-III(N-3)(2)(pao)(10)(hmcH)(2)(OH)(4)]Br center dot 2MeOH center dot 9H(2)O (2 center dot 2MeOH center dot 9H(2)O), [(MnNi5II)-Ni-III(N-3)(4)(pao)(6)(paoH)(2)(OH)(2)](CiO(4))center dot MeOH center dot 3H(2)O (3 center dot MeOH center dot 3H(2)O), and [(Mn2Ni2II)-Ni-III(hmcH)(2)(pao)(4)(OMe)(2)(MeOH)(2)]center dot 2H(2)O center dot 6MeOH (4 center dot 2H(2)O center dot 6MeOH) [paoH = Pyridine-2-aldoxime, hmcH(3) = 2, 6-Bis(hydroxymethyl)-p-cresol], has been prepared by reactions of Mn(II) salts with [Ni(paoH)(2)Cl-2], hmcH(3), and NEt3 in the presence or absence of NaN3 and characterized. Complex 1 has a (Mn4Ni5II)-Ni-III topology which can be described as two corner-sharing [Mn2Ni2O2] butterfly units bridged to an outer Mn atom and a Ni atom through alkoxide groups. Complex 2 has a (Mn3Ni6II)-Ni-III topology that is similar to that of 1 but with. two corner-sharing [Mn2Ni2O2] units of 1 replaced with [Mn3NiO2] and [MnNi3O2] units as well as the outer Mn atom of 1 substituted by a Ni atom. 1 and 2 represent the largest 3d heterometal/oxime clusters and the biggest (MnNiII)-Ni-III clusters discovered to date. Complex 3 possesses a [MnNi5(mu-N-3)(2)(mu-OH)(2)](9+) core, whose topology is observed for the first time in a discrete molecule. Careful examination of the structures of 1-3 indicates that the Mn/Ni ratios of the complexes are likely associated with the presence of the different coligands hmcH(2-) and/or N-3(-). Complex 4 has a Mn(III)2Ni(2)(II) defective double-cubane topology. Variable-temperature, solid-state dc and ac magnetization studies were carried out on complexes 1-4. Fitting of the obtained M/(N mu(B)) vs H/T data gave S = 5, g = 1.94, and D = -0.38 cm(-1) for 1 and S = 3, g = 2.05, and D = -0.86 cm(-1) for 3. The ground state for 2 was determined from ac data, which indicated an S = 5 ground state. For 4, the pairwise exchange interactions were determined by fitting the susceptibility data vs T based on a 3-J model. Complex 1 exhibits out-of-phase ac susceptibility signals, indicating it may be a SMM.
• An investigation of some homo- and heterobinuclear complexes of copper(II) and nickel(II) with pyridine-2-aldoxime
  作者：R. Bucci、V. Carunchio、A. D. Magrí、A. L. Magrí

  DOI：10.1007/bf01913192

  日期：1988.3