place in the series of oxochloride complexes of Re(VII), Re(VI), and Re(V) in concentrated hydrochloric and sulfuric acids and their mixtures. The kinetics of the formation and decay of the short-lived complex ReOCl5−have been studied as a function, of the composition of the medium (the concentration of the acids and water). The causes of the stabilization of ReOC5−in concentrated H2SO4 have been elucidated
脉冲光解已用于研究在浓
盐酸和
硫酸及其混合物中 Re(VII)、Re(VI) 和 Re(V) 的一系列氧
氯化物络合物中发生的光
化学反应。短寿命复合物 ReOCl5- 的形成和衰变动力学已被研究为介质组成(酸和
水的浓度)的函数。ReOC5-在浓
硫酸中稳定的原因已经阐明。已经发现在 HCl 光解中形成的阴离子自由基 Cl2-将复合物 ReOCl52-氧化为 ReOCl5-。