trans-[RuCl2(Mn(CO)3(C4PH2(CH3)2))4] | 159100-10-4

• 英文名称: trans-[RuCl2(Mn(CO)3(C4PH2(CH3)2))4]
• CAS: 159100-10-4
• 化学式: C₃₆H₃₂Cl₂Mn₄O₁₂P₄Ru
• 分子量: 1172.27
• InChiKey: DKHCJMNVVDNJLB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  trans-[RuCl2(Mn(CO)3(C4PH2(CH3)2))4] 在 pyridine 作用下， 以 甲苯 为溶剂， 以57%的产率得到
  参考文献：
  名称：

  Ruthenium(II) complexes of 3,4-dimethylphosphacymantrene

  摘要：

  A series of RuCl2 complexes of 3,4-dimethylphosphacymantrene (L) have been synthesized. Their structures were established on the basis of H-1, C-13, P-31 NMR and IR spectroscopy. Two of them, trans-[RuCl2(L)4] and cis,cis,trans-[RuCl2(CO)2(L)2] were characterized by X-ray crystal structure analysis, and show the ligands L to bond via normal P-Ru sigma bonds, with Ru-P distances in the range 2.288(1)-2.339(1) angstrom.

  DOI：

  10.1016/s0277-5387(00)83099-5
• 作为产物：
  描述：

  水合三氯化钌 、 3,4-dimethylphosphacymanthrene 以 甲醇 为溶剂， 以43%的产率得到trans-[RuCl2(Mn(CO)3(C4PH2(CH3)2))4]
  参考文献：
  名称：

  Ruthenium(II) complexes of 3,4-dimethylphosphacymantrene

  摘要：

  A series of RuCl2 complexes of 3,4-dimethylphosphacymantrene (L) have been synthesized. Their structures were established on the basis of H-1, C-13, P-31 NMR and IR spectroscopy. Two of them, trans-[RuCl2(L)4] and cis,cis,trans-[RuCl2(CO)2(L)2] were characterized by X-ray crystal structure analysis, and show the ligands L to bond via normal P-Ru sigma bonds, with Ru-P distances in the range 2.288(1)-2.339(1) angstrom.

  DOI：

  10.1016/s0277-5387(00)83099-5