| 402826-82-8

• CAS: 402826-82-8
• 化学式: C₄₀H₇₈Ir₂N₆P₂
• 分子量: 1089.49
• InChiKey: YBGYASYJRIGZQD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 氘代苯 为溶剂， 生成
  参考文献：
  名称：

  Sequential C−H Activation and Dinuclear Insertion of Ethylene Promoted by a Diiridium Complex

  摘要：

  Two ethylene molecules, bonded to different metal atoms of a diiridium(I) complex, can be converted into a bridging 3-butenyl-1-yl ligand and a terminal hydride. Such transformation is initiated by an ethylene C-H activation step and followed by an insertion of the second ethylene into a bridging vinyl ligand. This result illustrates the potentiality of diiridium(I) complexes to promote and support reaction sequences of alkene functionalization through C-H activation.

  DOI：

  10.1021/ja016753i
• 作为产物：
  描述：

  、 三异丙基膦 以 甲苯 为溶剂， 生成
  参考文献：
  名称：

  Sequential C−H Activation and Dinuclear Insertion of Ethylene Promoted by a Diiridium Complex

  摘要：

  Two ethylene molecules, bonded to different metal atoms of a diiridium(I) complex, can be converted into a bridging 3-butenyl-1-yl ligand and a terminal hydride. Such transformation is initiated by an ethylene C-H activation step and followed by an insertion of the second ethylene into a bridging vinyl ligand. This result illustrates the potentiality of diiridium(I) complexes to promote and support reaction sequences of alkene functionalization through C-H activation.

  DOI：

  10.1021/ja016753i