[In(Me)2(dicyclohexylformamidine)]2 | 174365-10-7

• 英文名称: [In(Me)2(dicyclohexylformamidine)]2
• CAS: 174365-10-7
• 化学式: C₃₀H₅₈In₂N₄
• 分子量: 704.457
• InChiKey: LNMJXALURFNJHC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [In(Me)2(dicyclohexylformamidine)]2 、 N,N'-di-cyclohexylformamidine 以 not given 为溶剂， 以85%的产率得到[In(Me)(dicyclohexylformamidine)2]2
  参考文献：
  名称：

  新型桥联双核铟配合物的合成与结构。

  摘要：

  The unique, lantern-type structure of 1 has two In centers in unusual square-based pyramidal environments consisting of the four formamidinate N atoms with a terminal chloride occupying the apical position. Two routes for the formation of 1 and a stepwise pathway for the preparation of the dimethyl analogue are presented. Without the possibility of In-In interactions it would appear that steric features are the primary cause for the formation of these compounds.

  DOI：

  10.1021/ic951241o
• 作为产物：
  描述：

  N,N'-di-cyclohexylformamidine 、 三甲基铟 以 not given 为溶剂， 生成 [In(Me)2(dicyclohexylformamidine)]2
  参考文献：
  名称：

  新型桥联双核铟配合物的合成与结构。

  摘要：

  The unique, lantern-type structure of 1 has two In centers in unusual square-based pyramidal environments consisting of the four formamidinate N atoms with a terminal chloride occupying the apical position. Two routes for the formation of 1 and a stepwise pathway for the preparation of the dimethyl analogue are presented. Without the possibility of In-In interactions it would appear that steric features are the primary cause for the formation of these compounds.

  DOI：

  10.1021/ic951241o