Synthesis and reactions of phosphido-bridged μ3-alkylidyne clusters; X-ray crystal structures of the complexes [Co2W(μ-PEt2)3(CO)5(η-C5H5)], [Co2W{μ3-C(R)C(Et)C(Et)C(O)}(μ-CO)(CO)4(PPh2{C(Et)CHEt})(η-C5H5)], and [CoW{μ-C(R)C(Et)C(Et)C(OH)}(CO)4(η-C5H5)] (R = C6H4Me-4)
摘要:
DOI:
10.1016/0022-328x(86)80267-4
作为产物:
描述:
{WCo2(μ3-CC6H4Me-4)(CO)8(η-C5H5)} 、 二乙基膦 以
not given 为溶剂,
以60-70的产率得到
参考文献:
名称:
Synthesis and reactions of phosphido-bridged μ3-alkylidyne clusters; X-ray crystal structures of the complexes [Co2W(μ-PEt2)3(CO)5(η-C5H5)], [Co2W{μ3-C(R)C(Et)C(Et)C(O)}(μ-CO)(CO)4(PPh2{C(Et)CHEt})(η-C5H5)], and [CoW{μ-C(R)C(Et)C(Et)C(OH)}(CO)4(η-C5H5)] (R = C6H4Me-4)