benzyltriphenylphosphonium pentachloridooxidorhenate(VI) | 1166850-61-8

• 英文名称: benzyltriphenylphosphonium pentachloridooxidorhenate(VI)
• CAS: 1166850-61-8
• 化学式: C₂₅H₂₂P*Cl₅ORe
• 分子量: 732.895
• InChiKey: DZCUVJHBQZTDJL-UHFFFAOYSA-I

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  盐酸 、 benzyltriphenylphosphonium rhenate(VII) 以 异丙醇 为溶剂， 生成 benzyltriphenylphosphonium pentachloridooxidorhenate(VI)
  参考文献：
  名称：

  New insight into the reduction of rhenates(VII) with hydrogen chloride and into the structure of the product

  摘要：

  Rhenate(VII) anion is reduced by gaseous HCl to yield pentachloridooxidorhenate(VI) anion. Several pentachloridooxidorhenate( VI) salts have been crystallized and the anion structure has been investigated in detail. The ReOCl5- anion structure has been compared with the ReOCl52- structure and conclusions concerning the influence of the central atom d electrons number on the anion geometry have been drawn. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.01.035