ammonium cesium tetrachlorozincate(II) | 1297609-81-4

• 英文名称: ammonium cesium tetrachlorozincate(II)
• CAS: 1297609-81-4
• 化学式: Cl₄Zn*Cs*H₄N
• 分子量: 358.146
• InChiKey: OOBSRLZRWADIIM-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cesium chloride 、 ammonium chloride 、 zinc(II) chloride 以 水 为溶剂， 生成 ammonium cesium tetrachlorozincate(II)
  参考文献：
  名称：

  1H and 133Cs nuclear magnetic resonance study of the NH4 and Cs occupation rates of mixed (NH4)2−xCsxZnCl4 (x=0, 1, and 2) crystals

  摘要：

  The NMR spectra and the spin-lattice relaxation times, T-1, of the H-1 and Cs-133 nuclei in (NH4)(2) xCsxZnCl4 (x = 0, 1, and 2) single crystals were determined by using NMR spectroscopy. We investigated the crystallographic structures of these crystals by determining the NH4 and Cs occupation probabilities of the two cationic sites. Our NMR experimental results confirm that in (NH4) 2ZnCl4 there are two crystallographically inequivalent NH4 groups, NH4(1) and NH4(2), occupying the A(1) and A(2) sites, and that in Cs2ZnCl4 there are two crystallographically inequivalent Cs ions, Cs(1) and Cs(2), occupying the A(1) and A(2) sites. Both types of NH4 ions and both types of Cs ions are found in mixed NH4CsZnCl4 crystals; the occupation rates of the two different sites are 1 and 1 for Cs(1) and Cs(2), respectively, and 1 and 1 for NH4(1) and NH4(2), respectively. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.chemphys.2012.01.027