aluminium(III) bis(2-methyl-5-phenyl-8-quinolinolate)phenolate | 848902-77-2

• 英文名称: aluminium(III) bis(2-methyl-5-phenyl-8-quinolinolate)phenolate
• CAS: 848902-77-2
• 化学式: C₃₈H₂₉AlN₂O₃
• 分子量: 588.641
• InChiKey: QOWWFPSDQPDRJU-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  aluminium(III) phenoxide 、 5-phenyl-2-methylquinolin-8-ol 以 not given 为溶剂， 生成 aluminium(III) bis(2-methyl-5-phenyl-8-quinolinolate)phenolate
  参考文献：
  名称：

  True Blue:  Blue-Emitting Aluminum(III) Quinolinolate Complexes

  摘要：

  Blue-emitting heteroleptic aluminum(III) bis(2-methyl-8-quinolinolate) phenolate complexes were synthesized. A tunable, blue-to-green emission is achieved by attaching electron-withdrawing modulators to the emisssive quinaldinate ligand. The electronic nature of modulator substituents attached to the position of the highest HOMO (highest occupied molecular orbital) density is used to modulate ligand HOMO levels to achieve effective emission tuning to obtain blue-emitting materials. Optical and electrochemical properties of the resulting complexes were investigated and compared to the results of density functional theory (DFT/B3LYP/6-31G*) studies. The resulting materials may find application as organic light-emitting device materials.

  DOI：

  10.1021/ic061051l