| 218136-37-9

• CAS: 218136-37-9
• 化学式: C₇₇H₂₁FeNO₃
• 分子量: 1063.87
• InChiKey: XTPQPXYSQHJVOH-IOPFKDIVSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 碘甲烷 以 氯仿 为溶剂， 生成
  参考文献：
  名称：

  Enhanced Acceptor Character in Fullerene Derivatives. Synthesis and Electrochemical Properties of Fulleropyrrolidinium Salts

  摘要：

  A family of N-methylpyrrolidinium fullerene iodide salts, possessing one (or two) solubilizing chain(s), has been synthesized. As evidenced by CV and steady-state voltammetry experiments, carried out in tetrahydrofuran (THF) solutions, these species show enhanced electron-accepting properties with respect to both the parent fulleropyrrolidines and C-60 CV measurements performed at -60 degrees C and scan rates of 50 V/s, made possible by the use of ultramicroelectrodes,: have allowed the observation, for the first time in fullerene derivatives, of six fullerene-centered reductions. Bulk electrolysis of these novel compounds, performed at the stage of the first reduction potential, generates a stable zwitterion, with both anion and cation located on the fullerene derivative.

  DOI：

  10.1021/ja9827705
• 作为产物：
  描述：

  聚合甲醛 、 、 足球烯 以 甲苯 为溶剂， 以10%的产率得到
  参考文献：
  名称：

  Enhanced Acceptor Character in Fullerene Derivatives. Synthesis and Electrochemical Properties of Fulleropyrrolidinium Salts

  摘要：

  A family of N-methylpyrrolidinium fullerene iodide salts, possessing one (or two) solubilizing chain(s), has been synthesized. As evidenced by CV and steady-state voltammetry experiments, carried out in tetrahydrofuran (THF) solutions, these species show enhanced electron-accepting properties with respect to both the parent fulleropyrrolidines and C-60 CV measurements performed at -60 degrees C and scan rates of 50 V/s, made possible by the use of ultramicroelectrodes,: have allowed the observation, for the first time in fullerene derivatives, of six fullerene-centered reductions. Bulk electrolysis of these novel compounds, performed at the stage of the first reduction potential, generates a stable zwitterion, with both anion and cation located on the fullerene derivative.

  DOI：

  10.1021/ja9827705