bis(((3-(4-methoxyphenyl)-5,5-dimethylisoxazolidin-2-yl)methylene)amino)platinum(VI) chloride | 1204200-83-8

• 英文名称: bis(((3-(4-methoxyphenyl)-5,5-dimethylisoxazolidin-2-yl)methylene)amino)platinum(VI) chloride
• CAS: 1204200-83-8
• 化学式: C₂₆H₃₆Cl₄N₄O₄Pt
• 分子量: 805.488
• InChiKey: LVWUHPBWWKPHGY-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  在 H₂O 作用下， 以 氘代氯仿 为溶剂， 生成 bis(((3-(4-methoxyphenyl)-5,5-dimethylisoxazolidin-2-yl)methylene)amino)platinum(VI) chloride
  参考文献：
  名称：

  Interplay between nitronates and nitriles accomplished in a PtIV-mediated reaction

  摘要：

  Reaction between the coordinated propanenitriles in trans-[PtCl4(EtCN)(2)] and the cyclic nitronate ON=CHCH(C6H4OMe)CH2CMe2O (1) gives the N-acylated iminocomplex [PtCl4{N(CEtO)=CHNOCH(C6H4OMe)CH2CMe2}(2)] (2) which is unstable in wet solvents and undergoes hydrolysis to furnish [PtCl4{NH=CHNOCH(C6H4OMe)CH2CMe2}(2)] (3). The formulation of 2 and 3 was supported by satisfactory C, H, and N elemental analyses, agreeable HRESI+-MS, IR, H-1 NMR spectroscopies, and single-crystal X-ray diffraction (for trans-3). (c) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2008.12.006