| 717143-62-9

• CAS: 717143-62-9
• 化学式: C₆H₆*C₃₂H₄₂ClNOSU
• 分子量: 840.353
• InChiKey: AWNMOMAZLMCOGN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 not given 为溶剂， 生成 、
  参考文献：
  名称：

  Uranium-sulfilimine chemistry. Hydrolysis of Cp*2UCl2 with HNSPh2·H2O and the crystal structure of Cp*2UCl(OH)(HNSPh2), a metallocene terminal hydroxy complex of tetravalent uranium

  摘要：

  The reaction of Cp*2UCl2(HNSPh2) with HNSPh2 (.) H2O in 1: 1 stoichiometry, produces Cp*2UC(OH)(HNSPh2) in good yield. This is the first structurally characterized metallocene f-element complex containing a terminal hydroxy ligand. Cp*2UCl(OH)(HNSPh2) is an intermediate in the formation of a tetra uranium-oxo-cluster [Cp*(Cl)(HNSPh2)U(mu(3)-O)(mu(2)-O)U(Cl)(HNSPh2)(2)](2), which forms by hydrolysis of Cp*2UCl2 with excess HNSPh2 (.) H2O. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.03.029
• 作为产物：
  描述：

  S,S-二苯基硫亚胺一水合物 、 、 苯 以 苯 为溶剂， 以63.7%的产率得到
  参考文献：
  名称：

  Uranium-sulfilimine chemistry. Hydrolysis of Cp*2UCl2 with HNSPh2·H2O and the crystal structure of Cp*2UCl(OH)(HNSPh2), a metallocene terminal hydroxy complex of tetravalent uranium

  摘要：

  The reaction of Cp*2UCl2(HNSPh2) with HNSPh2 (.) H2O in 1: 1 stoichiometry, produces Cp*2UC(OH)(HNSPh2) in good yield. This is the first structurally characterized metallocene f-element complex containing a terminal hydroxy ligand. Cp*2UCl(OH)(HNSPh2) is an intermediate in the formation of a tetra uranium-oxo-cluster [Cp*(Cl)(HNSPh2)U(mu(3)-O)(mu(2)-O)U(Cl)(HNSPh2)(2)](2), which forms by hydrolysis of Cp*2UCl2 with excess HNSPh2 (.) H2O. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.03.029