(1,5,9-trimesityldipyrromethene)FeCl(pyridine) | 1114543-37-1

• 英文名称: (1,5,9-trimesityldipyrromethene)FeCl(pyridine)
• 英文别名: (1,5,9-trimesityldipyrrinato)FeCl(pyridine)；(1,5,9-trimesityldipyrrinato)FeCl(py)；(pyac)FeCl(pyr)
• CAS: 1114543-37-1
• 化学式: C₄₁H₄₂ClFeN₃
• 分子量: 668.105
• InChiKey: IDLOFONVODISHG-MNDWRGKASA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  叠氮金刚烷 、 (1,5,9-trimesityldipyrromethene)FeCl(pyridine) 以 neat (no solvent, solid phase) 为溶剂， 生成 (1,5,9-trimesityldipyrromethene)FeCl(NHAd)
  参考文献：
  名称：

  C−H Bond Amination from a Ferrous Dipyrromethene Complex

  摘要：

  In this Communication, we report an intramolecular C-H bond amination reaction of a dipyrromethene ferrous complex with organic azides. Monitoring of the spectral changes (variable-temperature NMR and UV-vis) of the Fell complex reveals no buildup of an intermediate during conversion of the starting material into the nitrene-inserted product. The rate-determining step appears to be azide addition to the 14-electron FeII complex, hinting at the potential that these and related platforms may have to effect atom- and group-transfer processes.

  DOI：

  10.1021/ic900219b
• 作为产物：
  描述：

  吡啶 、 (1,5,9-trimesityldipyrromethene)FeCl(THF) 以 吡啶 为溶剂， 生成 (1,5,9-trimesityldipyrromethene)FeCl(pyridine)
  参考文献：
  名称：

  C−H Bond Amination from a Ferrous Dipyrromethene Complex

  摘要：

  In this Communication, we report an intramolecular C-H bond amination reaction of a dipyrromethene ferrous complex with organic azides. Monitoring of the spectral changes (variable-temperature NMR and UV-vis) of the Fell complex reveals no buildup of an intermediate during conversion of the starting material into the nitrene-inserted product. The rate-determining step appears to be azide addition to the 14-electron FeII complex, hinting at the potential that these and related platforms may have to effect atom- and group-transfer processes.

  DOI：

  10.1021/ic900219b

文献信息

• Electronic Perturbations of Iron Dipyrrinato Complexes via Ligand β-Halogenation and <i>meso</i>-Fluoroarylation
  作者：Austin B. Scharf、Theodore A. Betley

  DOI：10.1021/ic2009539

  日期：2011.7.18

  proligand reductions (E1/2: −1.25 to −1.99 V) and oxidations (E1/2: +0.52 to +1.14 V vs [Cp2Fe]+/0). Installation of iron into the dipyrrinato scaffolds was effected via deprotonation of the proligands followed by treatment with FeCl2 and excess pyridine in tetrahydrofuran to afford complexes of the type (β,ArL)FeCl(py) (py = pyridine). The electrochemical and spectroscopic behavior of these complexes varies

  通过吡咯β-位的卤化和/或通过在配体桥头位置使用氟化的芳基取代基，将系统电子变化引入单阴离子二吡喃酮配体骨架中，以合成1,9-二甲磺酰基-β-型的配体R 4 -5-Ar-联吡啶[R = H，Cl，Br，I; Ar ＝ 1，3，5-（F 3 C）2 C 6 H 3，C 6 F 5在配体5位。β= 2,3,7,8配体取代; 缩写（β，ArL）H]。使用标准的电子吸收和电化学技术，对不同的配体变化及其二价铁配合物探测电子扰动。自由配体的变化会引起电子吸收最大值的适度偏移（λmax：464–499 nm），单电子配体减少的电化学氧化还原电位的偏移更为明显（E 1/2：-1.25至-1.99 V）和氧化（E 1/2：+0.52至+1.14 V对[Cp 2 Fe] + / 0）。通过将配体进行去质子化，然后用FeCl 2处理，将铁安装到双吡啶类支架中和过量的吡啶在四氢呋喃中提供类型（β，Ar L）FeCl（py）（py