| 1446828-57-4

• CAS: 1446828-57-4
• 化学式: CH₄O*C₂₀H₂₄Cl₃N₄OSm
• 分子量: 625.198
• InChiKey: SAXPDAQGNCBDFJ-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  反应 5.0h， 生成 samarium(III) oxide
  参考文献：
  名称：

  Synthesis, characterization and crystal structure of three new lanthanide (III) complexes with the [(6-methyl-2-pyridyl)methyl]bis(2-pyridylmethyl)amine (MeTPA) ligand; New precursors for lanthanide (III) oxide nano-particles

  摘要：

  Several novel lanthanum (III) complexes of the [(6-methyl-2-pyridyl)methyl]bis(2-pyridylmethyl)amine (MeTPA) ligand with the formula [Ln(MeTPA)Cl-3(MeOH)]center dot MeOH (Ln: La (1), Nd (2) and Sm (3)) were successfully synthesized. The complexes were characterized by H-1 NMR, mass spectrometry, TGA-DTA as well as elemental analysis. The molecular structures of the three complexes were determined by single-crystal X-ray crystallography. The single-crystal X-ray data revealed that 1, 2 and 3 are isostructural. The prepared complexes have been used as new precursors for the preparation of the related nano-oxides. The crystallinity and morphology of the Ln(III)-oxide nano-particles were characterized by powder X-ray diffraction (XRD) and scanning electron microscopy (SEM). (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.04.061
• 作为产物：
  描述：

  甲醇 、 samarium(III) chloride hexahydrate 、 ((6-methyl-2-pyridyl)methyl)bis(2-pyridylmethyl)amine 以 乙醚 、 二氯甲烷 为溶剂， 反应 72.0h， 以48%的产率得到
  参考文献：
  名称：

  Synthesis, characterization and crystal structure of three new lanthanide (III) complexes with the [(6-methyl-2-pyridyl)methyl]bis(2-pyridylmethyl)amine (MeTPA) ligand; New precursors for lanthanide (III) oxide nano-particles

  摘要：

  Several novel lanthanum (III) complexes of the [(6-methyl-2-pyridyl)methyl]bis(2-pyridylmethyl)amine (MeTPA) ligand with the formula [Ln(MeTPA)Cl-3(MeOH)]center dot MeOH (Ln: La (1), Nd (2) and Sm (3)) were successfully synthesized. The complexes were characterized by H-1 NMR, mass spectrometry, TGA-DTA as well as elemental analysis. The molecular structures of the three complexes were determined by single-crystal X-ray crystallography. The single-crystal X-ray data revealed that 1, 2 and 3 are isostructural. The prepared complexes have been used as new precursors for the preparation of the related nano-oxides. The crystallinity and morphology of the Ln(III)-oxide nano-particles were characterized by powder X-ray diffraction (XRD) and scanning electron microscopy (SEM). (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.04.061