| 157527-19-0

• CAS: 157527-19-0
• 化学式: CF₃O₃S*C₁₅H₂₂BN₆RuS₃
• 分子量: 643.529
• InChiKey: AYQVLEFYBUCXAS-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,4,7-三硫环壬烷 以 甲醇 、 氯仿 、 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Structure and reactions of the thioether half-sandwich ruthenium(II) complexes [Ru(MeCN)3([9]aneS3)][CF3SO3]2 and [Ru(MeCN)2(PPh3)([9]aneS3)][CF3SO3]2([9]aneS3= 1,4,7-trithiacyclononane)

  摘要：

  The complex [Ru(MeCN)3([9]aneS3)][CF3SO3]2 ([9]aneS3 = 1,4,7-trithiacyclononane) was prepared by reaction of [RuCl2(dmso)([9]aneS3)] 1 (dmso = dimethyl sulfoxide) with Ag(CF3SO3) in acetonitrile. It has been employed as a starting material for the synthesis of the mixed-ligand sandwich complexes [Ru{HB(pz)3}([9]aneS3)][CF3SO3] 3 (pz = pyrazol-1-yl) and [Ru{HC(pz)3}([9]aneS3)][CF3SO3]2 4 and the dinuclear half-sandwich complex [{Ru(mu-S2CNMe2)([9]aneS3)}2][CF3SO3]2 5. The complex [Ru(MeCN)2(PPh3)([9]aneS3)][CF3SO3]2 6 may likewise be used for the preparation of thioether half-sandwich ruthenium(II) complexes such as [Ru(S2CNMe2)(PPh3)([9]aneS3)][CF3SO3] 7 and [Ru(C7H4NS2)(PPh3)([9]aneS3)][CFSO3] 8 (C7H4NS2 = 2-sulfanylbenzothiazolate). The structures of 1, 2 and 5-7 have been determined by X-ray crystallography.

  DOI：

  10.1039/dt9940001885