1-isopropoxynonyl hydroperoxide | 544715-82-4

• 英文名称: 1-isopropoxynonyl hydroperoxide
• 英文别名: 1-Hydroperoxy-1-propan-2-yloxynonane
• CAS: 544715-82-4
• 化学式: C₁₂H₂₆O₃
• 分子量: 218.337
• InChiKey: WHNOKOGPBWFFNG-UHFFFAOYSA-N

物化性质

• 沸点：
  297.3±23.0 °C(Predicted)
• 密度：
  0.918±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  15
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  38.7
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1-isopropoxynonyl hydroperoxide 在 calcium hypochlorite 作用下， 以 乙腈 为溶剂， 反应 0.17h， 以93%的产率得到壬酸异丙酯
  参考文献：
  名称：

  Fragmentation of chloroperoxides: hypochlorite-mediated dehydration of hydroperoxyacetals to esters

  摘要：

  Hypochlorites efficiently dehydrate hydroperoxyacetals to furnish the corresponding esters. The reaction, which can be accomplished with stoichometric Ca(OCl)(2) or with catalytic amounts of t-BuOCl, appears to involve formation and heterolytic fragmentation of secondary chloroperoxides, species not previously described in solution chemistry. (c) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.08.068

文献信息

• Re₂O₇-catalyzed reaction of hemiacetals and aldehydes with <i>O</i>-, <i>S-,</i> and <i>C</i>-nucleophiles
  作者：Wantanee Sittiwong、Michael W Richardson、Charles E Schiaffo、Thomas J Fisher、Patrick H Dussault

  DOI：10.3762/bjoc.9.174

  日期：——

  monothioacetalization and allylation of hemiacetals. The reactions, which take place under mild conditions and at low catalyst loadings, can be conducted using hemiacetals, the corresponding O-silyl ethers, and, in some cases, the acetal dimers. Aldehydes react under similar conditions to furnish good yields of dithioacetals. Reactions of hemiacetals with nitrogen nucleophiles are unsuccessful. 1,2-Dioxolan-3-ols

  Re(VII) 氧化物催化半缩醛的缩醛化、单过氧缩醛化、单硫代缩醛化和烯丙基化。在温和条件和低催化剂负载下发生的反应可以使用半缩醛、相应的 O-甲硅烷基醚以及在某些情况下使用缩醛二聚体进行。醛在类似条件下反应以提供良好收率的二硫缩醛。半缩醛与含氮亲核试剂的反应不成功。1,2-Dioxolan-3-ols（过氧半缩醛）进行 Re(VII) 促进的醚化，但不进行烯丙基化。氢过氧缩醛（1-烷氧基氢过氧化物）在 Re2O7 或布朗斯台德酸存在下进行醇盐基团的选择性交换。
• Oil ozonolysis
  申请人：Fitchett Stanley Colin

  公开号：US20050010069A1

  公开（公告）日：2005-01-13

  Ozonolysis is a well known process involving reacting ozone with alkene compounds, for example in unsaturated vegetable oils or free fatty acids and esters thereof, to form ozonolysis products (e.g. ozonides). The invention concerns ozonolysis of unsaturated oils (e.g. unsaturated plant oils and/or unsaturated animal oils) in the presence of a participating co-reactant to form reaction products particularly suitable for use in the formation of resins.

  臭氧分解是一种众所周知的工艺，涉及臭氧与烯烃化合物（例如不饱和植物油或游离脂肪酸及其酯类中的烯烃化合物）反应，形成臭氧分解产物（例如臭氧化物）。本发明涉及不饱和油（如不饱和植物油和/或不饱和动物油）在参与共反应物存在下的臭氧分解，以形成特别适用于树脂形成的反应产物。
• OIL OZONOLYSIS
  申请人：Cambridge Biopolymers Limited

  公开号：EP1453799A1

  公开（公告）日：2004-09-08
• [EN] OIL OZONOLYSIS<br/>[FR] OZONOLYSE D'HUILES
  申请人：CAMBRIDGE BIOPOLYMERS LTD

  公开号：WO2003050081A1

  公开（公告）日：2003-06-19

  Ozonolysis is a well known process involving reacting ozone with alkene compounds, for example in unsaturated vegetable oils or free fatty acids and esters thereof, to form ozonolysis products (e.g. ozonides). The invention concerns ozonolysis of unsaturated oils (e.g. unsaturated plant oils and/or unsaturated animal oils) in the presence of a participating co-reactant to form reaction products particularly suitable for use in the formation of resins.