8-hydroxyquinolato carbonyl chlorobis(triphenylphosphine)ruthenium(II) | 93442-82-1

• 英文名称: 8-hydroxyquinolato carbonyl chlorobis(triphenylphosphine)ruthenium(II)
• 英文别名: RuCl(CO)(PPh3)2(8-hydroxyquinolinate)
• CAS: 93442-82-1；99295-73-5
• 化学式: C₄₆H₃₆ClNO₂P₂Ru
• 分子量: 833.268
• InChiKey: ZJHBRDZYKLPNOU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  8-hydroxyquinolato carbonyl chlorobis(triphenylphosphine)ruthenium(II) 、 silver perchlorate 在 CH₃CN 作用下， 以 乙腈 为溶剂， 以50%的产率得到[(acetonitrile)(quinoline-8-olato)carbonylbis(triphenylphosphine)ruthenium(II)] perchlorate
  参考文献：
  名称：

  Gopinathan, Sarada; Deshpande, S. S.; Gopinathan, C., Zeitschrift fur Anorganische und Allgemeine Chemie

  摘要：

  DOI：
• 作为产物：
  描述：

  8-羟基喹啉 、 [RuHCl(CO)(PPh₃)₃] 以 乙二醇甲醚 为溶剂， 以88%的产率得到8-hydroxyquinolato carbonyl chlorobis(triphenylphosphine)ruthenium(II)
  参考文献：
  名称：

  Joseph, K.; Gopinathan, Sarada; Gopinathan, C., Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1984, vol. 14, p. 1005 - 1012

  摘要：

  DOI：

文献信息

• The reactions of 8-hydroxyquinoline with [RuHCl(CO)(PPh3)3]: A new ruthenium(II) carbonyl complex with a N-donor ligand
  作者：J.G. Małecki、R. Kruszynski、Z. Mazurak

  DOI：10.1016/j.poly.2007.05.026

  日期：2007.9

  The reaction of [RuHCl(CO)(PPh3)(3)] with 8-hydroxyquinoline has been examined and a novel ruthenium(II) complex - [RuCl(CO)(PPh3)(2)(C9H6NO)] - has been obtained. This compound has been studied by IR, UV-Vis (absorption and emission), H-1 and P-31 NMR spectroscopy, and X-ray crystallography. The molecular orbital diagram of the complex has been calculated with the density functional theory (DFT) method. The spin-allowed singlet-singlet electronic transitions of the complex have been calculated with the time-dependent DFT method, and the UV-Vis spectrum of the compound has been discussed on this basis. (C) 2007 Elsevier Ltd. All rights reserved.