[Cu(2,2'-bipyridin-5-yl t-butyl nitroxide)Cl2] | 872005-92-0

• 英文名称: [Cu(2,2'-bipyridin-5-yl t-butyl nitroxide)Cl2]
• CAS: 872005-92-0
• 化学式: C₁₄H₁₆Cl₂CuN₃O
• 分子量: 376.753
• InChiKey: AQDZCCWNXZWQES-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,2'-bipyridin-5-yl t-butyl nitroxide 、 copper dichloride 以 甲醇 为溶剂， 生成 [Cu(2,2'-bipyridin-5-yl t-butyl nitroxide)Cl2]
  参考文献：
  名称：

  Magnetic properties of transition metal complexes with 2,2′-bipyridin-5-yl t-butyl nitroxide

  摘要：

  Complexes [Mn-11(5bpno)(3)(ClO4)(2)], [Mn-11(5bpno)(CH3OH)(2)Cl-2], [Cu-11(5bpno)(2)(ClO4)(2)], and [Cu-11(5bpno)Cl-2] were prepared, where 5bpno stands for 2,2'-bipyridin-5-yl t-butyl nitroxide. X-ray crystallographic analysis clarified that the Cu ion in [Cu(5bpno)(2)(ClO4)(2)] was tetra-coordinate with four nitrogen atoms forming two chelate rings. Magnetic measurements revealed the presence of ferromagnetic couplings in the Mn complexes, whereas the Cu complexes showed antiferromagnetic Couplings. Magnetic exchange couplings between the metal and radical spins through the intervening pyridine ring can be explained in terms of the spin-polarization mechanism. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.03.153