| 1227469-43-3

• CAS: 1227469-43-3
• 化学式: C₂₇H₃₄O₄Ru₂
• 分子量: 624.705
• InChiKey: AYEQXFDDGODRJR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 、 溴 以 二氯甲烷 为溶剂， 以80%的产率得到[((η5-C5Me4)(CH2)5(η5-C5Me4))(RuBr(CO)2)2]
  参考文献：
  名称：

  Rational Construction of Oligomeric Polymetallic Ensembles Consisting of Ru₂H₄ Subunits Interconnected by Flexible Carbon Chains

  摘要：

  Novel dinuclear ruthenium bromo-carbonyl complexes {(eta(5)-C5Me4)(CH2)(n)(eta(5)-C5Me4))}Ru-2(CO)(4)Br-2 (n = 4 (4a), 5 (4b), and 6 (4e)) are synthesized by the metalation of the corresponding bis(cyclopentadiene)-type ligands C5Me4H(CH2)(n)C5Me4H (n = 4, 5, and 6) with Ru-3(CO)(12), followed by bromination. Allylation of 4 with allyl bromide and subsequent treatment with LiEt3BH affords tetranuclear ruthenium octahydride complexes 6a-e, composed of two Ru2H4 sites. X-ray diffraction analysis reveals that the approximate geometry of the four ruthenium atoms in 6b is parallelogram

  DOI：

  10.1021/om100206a
• 作为产物：
  描述：

  十二羰基三钌 、 以 癸烷 为溶剂， 生成 、
  参考文献：
  名称：

  Rational Construction of Oligomeric Polymetallic Ensembles Consisting of Ru₂H₄ Subunits Interconnected by Flexible Carbon Chains

  摘要：

  Novel dinuclear ruthenium bromo-carbonyl complexes {(eta(5)-C5Me4)(CH2)(n)(eta(5)-C5Me4))}Ru-2(CO)(4)Br-2 (n = 4 (4a), 5 (4b), and 6 (4e)) are synthesized by the metalation of the corresponding bis(cyclopentadiene)-type ligands C5Me4H(CH2)(n)C5Me4H (n = 4, 5, and 6) with Ru-3(CO)(12), followed by bromination. Allylation of 4 with allyl bromide and subsequent treatment with LiEt3BH affords tetranuclear ruthenium octahydride complexes 6a-e, composed of two Ru2H4 sites. X-ray diffraction analysis reveals that the approximate geometry of the four ruthenium atoms in 6b is parallelogram

  DOI：

  10.1021/om100206a