(cyclopentadienyl)Fe(C5H4COOC6H3(CC)2)(Pt(PEt3)2(OTf))2 | 1073364-94-9

• 英文名称: (cyclopentadienyl)Fe(C5H4COOC6H3(CC)2)(Pt(PEt3)2(OTf))2
• CAS: 1073364-94-9
• 化学式: C₄₇H₇₂F₆FeO₈P₄Pt₂S₂
• 分子量: 1513.11
• InChiKey: MBWWDDVVYLNSLY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [((4-C5H4N)CC(4-C5H4N))Co2(CO)6] 、 (cyclopentadienyl)Fe(C5H4COOC6H3(CC)2)(Pt(PEt3)2(OTf))2 以 二氯甲烷 为溶剂， 生成 [((cyclopentadienyl)Fe(C5H4COOC6H3(CC)2)(Pt(PEt3)2)2)3(((4-C5H4N)CC(4-C5H4N))Co2(CO)6)3](OTf)6
  参考文献：
  名称：

  Construction of Coordination-Driven Self-Assembled [5 + 5] Pentagons Using Metal−Carbonyl Dipyridine Ligands

  摘要：

  The coordination-driven self-assembly of two metal-carbonyl-cluster-coordinated dipyridyl donors, (4-C5H4N)(2)C equivalent to CCo2(CO)(6) (1) and (4- C5H4N)(2)C equivalent to CMo2Cp2(CO)(4) (2), with a linear diplatinum (11) acceptor ligand was investigated. The structures of the resulting self-assembled polygons were found to be controlled by the steric bulk of the metal-carbonyl cluster adduct. The use of a sterically less imposing ligand 1 resulted in a pentagon-hexagon mixture, which was characterized by electrospray ionization time-of-flight mass spectroscopy. The exclusive formation of a [5 + 5] pentagon was achieved by the self-assembly of the bulkier molybdenum donor ligand 2 with a linear organoplatinum(II) acceptor ligand. Molecular force field modeling was used to study the structural details of the pentagonal and hexagonal architectures. The first Fe-3-Co-6-Pt-6 trimetal [3 + 3] hexagon was also synthesized via the combination of 1 with a 120 degrees ferrocenyldiplatinum(II) acceptor.

  DOI：

  10.1021/ic900649m

文献信息

• Ghosh, Koushik; Hu, Jiming; White, Henry S., Journal of the American Chemical Society, 2009, vol. 131, p. 6695 - 6697
  作者：Ghosh, Koushik、Hu, Jiming、White, Henry S.、Stang, Peter J.

  DOI：——

  日期：——
• Facile Self-Assembly of Dendritic Multiferrocenyl Hexagons and Their Electrochemistry
  作者：Guang-Zhen Zhao、Li-Jun Chen、Cui-Hong Wang、Hai-Bo Yang、Koushik Ghosh、Yao-Rong Zheng、Matthew M. Lyndon、David C. Muddiman、Peter J. Stang

  DOI：10.1021/om1008605

  日期：2010.11.22

  The design and synthesis of a new class of dendritic multiferrocenyl hexagons have been achieved via [3+3] coordination-driven self-assembly. The relative distribution of dendritic and ferrocenyl subunits on the periphery of supramolecular metallocycles can be precisely controlled. The structures of all compounds are confirmed by multinuclear NMR, ESI-MS/ESI-TOF-MS, and elemental analysis. The electrochemical properties of the newly designed dendritic multiferrocenyl complexes have been studied through cyclic voltammetry investigation.