Ru(p-CF₃TPP)CO | 917248-59-0

• 英文名称: Ru(p-CF₃TPP)CO
• 英文别名: Ru(p-CF3-TPP)CO；(carbonyl)(5,10,15,20-tetra(4-trifluoromethylphenyl)porphyrinato)ruthenium(II)；[Ru(4-(CF3) tetraphenylporphyrin-2H)CO]；Ru(II)(CO)(4-CF3-TPP)；[Ru(4-(CF3)TPP)CO]
• CAS: 917248-59-0
• 化学式: C₄₉H₂₄F₁₂N₄ORu
• 分子量: 1013.81
• InChiKey: NDXHWNYKFFGZIZ-YKKPBKTHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  3,5-bis(trifluoromethyl)phenyl azide 、 Ru(p-CF₃TPP)CO 以 苯 为溶剂， 反应 5.0h， 以50%的产率得到
  参考文献：
  名称：

  Synthesis of Biologically Relevant Compounds by Ruthenium Porphyrin Catalyzed Amination of Benzylic C–H Bonds

  摘要：

  Herein we report the catalytic activity of ruthenium porphyrin complexes to promote the amination of benzylic C-H bonds by aryl azides, yielding alpha- and beta-amino esters. The catalytic methodology is also effective to synthesize two derivatives of methyl L-3-phenyllactate in order to convert one of them into the corresponding beta-lactam. The catalytic experimental conditions have been optimized on the basis of a preliminary mechanistic investigation which underlines the pivotal role of the substrate concentration to maximize the reaction productivity.

  DOI：

  10.1021/om500064d

文献信息

• Generation of trans-dioxoruthenium(VI) porphyrins: A photochemical approach
  作者：Rui Zhang、Yan Huang、Chris Abebrese、Helen Thompson、Eric Vanover、Cathleen Webb

  DOI：10.1016/j.ica.2011.06.002

  日期：2011.10

  this type of compounds can be prepared by oxidation of ruthenium(II) precursors with peroxyacids and other terminal oxidants under different conditions, depending on the porphyrin ligands. In this work, a new photochemical generation of trans -dioxoruthenium(VI) porphyrins has been developed by extension of the known photo-induced ligand cleavage reactions. Refluxing ruthenium(II) carbonyl porphyrins

  摘要反式二氧杂卟啉（VI）卟啉配合物已被开发为含血红素的酶的最佳表征模型系统之一。传统上，取决于卟啉配体，可以通过在不同条件下用过氧酸和其他末端氧化剂氧化钌（II）前体来制备这类化合物。在这项工作中，通过扩展已知的光诱导配体裂解反应，已经开发出了一种新型的反式-二氧杂钌（VI）卟啉的光化学世代。在四氯化碳中回流钌（II）羰基卟啉[Ru II（Por）（CO）]，得到二氯钌（IV）络合物[Ru IV（Por）Cl 2]。将[Ru IV（Por）Cl 2]中的抗衡离子与Ag（ClO 3）或Ag（BrO 3）轻松交换，得到相应的二氯酸盐[Ru IV（Por）（ClO 3）2]或二溴酸盐[Ru IV（Por ）（BrO 3）2]盐。光不稳定的卟啉-钌（IV）二氯酸盐或二溴酸盐的可见光光解导致轴向配体中两个O-Cl或O-Br键的均相裂解，从而生成反式-二氧杂钌（IV）物种[Ru VI（ （Por）O
• A mechanistic investigation of the ruthenium porphyrin catalysed aziridination of olefins by aryl azides
  作者：P. Zardi、A. Pozzoli、F. Ferretti、G. Manca、C. Mealli、E. Gallo

  DOI：10.1039/c5dt00951k

  日期：——

  A mechanism for the aziridination of olefins by aryl azides (ArN3), promoted by ruthenium(II) porphyrin complexes, is proposed on the basis of kinetic and theoretical studies. All the recorded data support the involvement of a mono-imido ruthenium complex as the active intermediate in the transfer of the nitrene moiety “ArN” to the olefin. The selectivity of the aziridination vs. the uncatalysed triazoline

  在动力学和理论研究的基础上，提出了钌（II）卟啉配合物促进芳基叠氮化物（ArN 3）进行烯烃叠氮的机理。所有记录的数据都支持单亚氨基钌配合物作为活性中间体参与腈部分“ ArN”向烯烃的转移。可以通过微调卟啉配体的电子特征和烯烃/叠氮化物的催化比来提高叠氮化与非催化三唑啉形成的选择性。DFT研究强调了中间钌单亚胺基配合物的三重态基态的重要性，以使叠氮化过程得以发展。
• Cyclic voltammetric and fiber-optic infrared spectroelectrochemical studies of six-coordinate (por)Ru(NO)Cl compounds (por=porphyrinato dianion)
  作者：Mona A. El-Attar、Nan Xu、Dennis Awasabisah、Douglas R. Powell、George B. Richter-Addo

  DOI：10.1016/j.poly.2012.03.034

  日期：2012.6

  The redox behavior of representative (por)Ru(NO)Cl complexes (por = OEP, T(p-OMe)PP, T(p-CF3)PP) have been obtained. The compounds possess linear RuNO moieties as exemplified by the X-ray crystal structure of (T(p-OMe)PP)Ru(NO)Cl (Ru-N-O = 174(2)degrees, Ru-N(O) = 1.790(17) angstrom, Ru-Cl = 2.220(6) angstrom). The first electrooxidations of the (por)Ru(NO)Cl compounds in CH2Cl2 occur in the order OEP (+0.51 V) < T(p-OMe)PP (+0.57 V) < T(p-CF3)PP (+0.84 V) (versus Fc/Fc(+)). We have utilized infrared reflectance spectroelectrochemistry to determine that the first oxidations are porphyrin centered. In addition, the reductions are largely RuNO centered. (C) 2012 Elsevier Ltd. All rights reserved.