| 745024-76-4

• CAS: 745024-76-4
• 化学式: C₅₉H₇₈AlN₃
• 分子量: 856.27
• InChiKey: DBDNHSPUDSWIRU-NODCXOIRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  以 正己烷 、 甲苯 为溶剂， 生成
  参考文献：
  名称：

  Two Types of Intramolecular Addition of an Al−N Multiple-Bonded Monomer LAlNAr‘ Arising from the Reaction of LAl with N₃Ar‘ (L = HC[(CMe)(NAr)]₂, Ar‘ = 2,6-Ar₂C₆H₃, Ar = 2,6-iPr₂C₆H₃)

  摘要：

  The reaction of beta-diketiminated aluminum(I) monomer LAl with a large bulky azide N3Ar' (L = HC(CMeNAr)2, Ar' = 2,6-Ar2C6H3, Ar = 2,6-iPr2C6H3) in the temperature range from -78 degrees C to room temperature affords two different isomers 2 and 3, which have been characterized by spectroscopic and X-ray structural analyses, as well as elemental analysis. The variable-temperature 1H NMR kinetic studies of this reaction indicate the existence of the monomer LAlNAr' (1) at low temperature and the thermal stability of the compounds increases in the order of 1 < 2 < 3.

  DOI：

  10.1021/ja0475712