hexachloro(bis(diphenylphosphino)amine)digold(III) | 1011490-75-7

• 英文名称: hexachloro(bis(diphenylphosphino)amine)digold(III)
• CAS: 1011490-75-7
• 化学式: C₂₄H₂₁Au₂Cl₆NP₂
• 分子量: 992.036
• InChiKey: WJRFKTFQGMNLSK-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [Au(tht)2](CF3SO3) 、 1-benzyl-2-(4'-chlorophenylazo)imidazole 、 hexachloro(bis(diphenylphosphino)amine)digold(III) 以 二氯甲烷 为溶剂， 生成 dichloro(bis(diphenylphosphino)amine)bis(1-benzyl-2-(p-chlorophenylazo)imidazole)digold(III) triflate
  参考文献：
  名称：

  Gold(III)-chloro-diphenylphosphinoammine-arylazoimidazole complexes: Synthesis, spectroscopic and redox study

  摘要：

  The complex [Au-III(dppa)Cl-2(tht)(4)](OSO2CF3), with ligand addition produce [Au-III(dppa)Cl-2(RaaiR')(2)](OTf)(4) [RaaiR'=p-R-C-6 H-4-N=N-C3H2 -NN-1-R', (1-3), abbreviated as N,N'-chelator, where N(imidazole) and N(azo) represent N and N', respectively; R = H (a), Me (b), Cl (c) and R' = Me (1), CH2CH3 (2), CH2Ph (3), dppa is diphenylphosphinoamine, OSO2CF3 is triflate anion, tht is tetrahydrothiophen]. IR spectra of the complexes show -C=N- and -N=N- stretching near at 1590 and 1370 cm(-1) and near at 1100, 755, 695, 545, 505 cm-1 for dppa. The H-1 NMR spectral measurements suggest methylene, -CH2-, in [Au-2(dppa)Cl-2(RaaiCH(2)CH(3))(2)](4+), giving a complex AB type multiplet splitting while in [Au-2(dppa)Cl-2(RaaiCH(2)Ph)(2)](4+), AB type quartet splitting. C-13 (H-1) NMR spectrum suggest the molecular skeleton. Electrochemistry show the ligand reductions at the negative to SCE. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2007.03.014