[(cyclopentadienyl)Mo(CO)2GeC(SiMe3)3] | 1354770-84-5

• 英文名称: [(cyclopentadienyl)Mo(CO)2GeC(SiMe3)3]
• 英文别名: [Cp(CO)2MoGeC(SiMe3)3]
• CAS: 1354770-84-5
• 化学式: C₁₇H₃₂GeMoO₂Si₃
• 分子量: 521.226
• InChiKey: ISJYAVPZTQROHH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [(cyclopentadienyl)Mo(CO)2GeC(SiMe3)3] 、 1,3,4,5-tetramethylimidazol-2-ylidene 以 甲苯 为溶剂， 以69%的产率得到[(cyclopentadienyl)Mo(CO)2GeC(SiMe3)3(tetramethylimidazol-2-ylidene)]
  参考文献：
  名称：

  Metal Activation of a Germylenoid, a New Approach to Metal–Germanium Triple Bonds: Synthesis and Reactions of the Germylidyne Complexes [Cp(CO)₂M≡Ge–C(SiMe₃)₃] (M = Mo, W)

  摘要：

  The reactions of the germylenoid Li(THF)(3)GeCl2C(SiMe3)(3) with the carbonyl metalates Li[CpMo(CO)(3)] and K[CpW(CO)(3)] (Cp = eta(5)-C5H5) in toluene afford selectively the germylidyne complexes [Cp(CO)(2)M Ge-C(SiMe3)(3)] (1-Mo, M = Mo; 1-W, M = W). The compounds 1-Mo and 1-W rapidly add 1,3,4,5-tetramethylimidazol-2-ylidene (Im-Me-4) at the electrophilic germanium center to give the zwitterionic germylidene complexes [Cp(CO)(2)M=Ge (Im-Me-4){C(SiMe3)(3)}] (2-Mo, M = Mo; 2-W, M = W). The molecular structures of 1-Mo/1-W and 2-Mo/2-W were determined by single-crystal X-ray diffraction studies, and the structural and spectroscopic features of all complexes are discussed.

  DOI：

  10.1021/om201176n
• 作为产物：
  描述：

  Li{Mo(CO)3(η5-C5H5)} 、 Li(THF)3GeCl2(C(Si(Me)3)3) 以 甲苯 为溶剂， 生成 [(cyclopentadienyl)Mo(CO)2GeC(SiMe3)3]
  参考文献：
  名称：

  Metal Activation of a Germylenoid, a New Approach to Metal–Germanium Triple Bonds: Synthesis and Reactions of the Germylidyne Complexes [Cp(CO)₂M≡Ge–C(SiMe₃)₃] (M = Mo, W)

  摘要：

  The reactions of the germylenoid Li(THF)(3)GeCl2C(SiMe3)(3) with the carbonyl metalates Li[CpMo(CO)(3)] and K[CpW(CO)(3)] (Cp = eta(5)-C5H5) in toluene afford selectively the germylidyne complexes [Cp(CO)(2)M Ge-C(SiMe3)(3)] (1-Mo, M = Mo; 1-W, M = W). The compounds 1-Mo and 1-W rapidly add 1,3,4,5-tetramethylimidazol-2-ylidene (Im-Me-4) at the electrophilic germanium center to give the zwitterionic germylidene complexes [Cp(CO)(2)M=Ge (Im-Me-4){C(SiMe3)(3)}] (2-Mo, M = Mo; 2-W, M = W). The molecular structures of 1-Mo/1-W and 2-Mo/2-W were determined by single-crystal X-ray diffraction studies, and the structural and spectroscopic features of all complexes are discussed.

  DOI：

  10.1021/om201176n