Tricarbonylnickel complexes of tetraarsenic and tetraphosphorus hexamethylimides
作者:Jean G. Riess、John R. Van Wazer
DOI:10.1016/s0022-328x(00)91048-9
日期:1967.5
Both tetraarsenic and tetraphosphorus hexamethylimide react with nickel tetracarbonyl to form complexes in which from one to four tricarbonylnickel groups coordinate with the arsenic or phosphorus atoms. The totally coordinated species are crystalline and insoluble in all common solvents whereas the other complexes have only been investigated in solution. Evidence is presented to show that complexing