trans-bis(1,2-bis(dimethylphosphino)ethane)(η2-H2)-hydridoruthenium(II)(1+) | 154508-00-6

• 英文名称: trans-bis(1,2-bis(dimethylphosphino)ethane)(η2-H2)-hydridoruthenium(II)(1+)
• 英文别名: trans-[Ru(1,2-bis(dimethylphosphino)ethane)2C(H2)H](1+)
• CAS: 154508-00-6；949596-64-9；949596-65-0
• 化学式: C₁₂H₃₅P₄Ru
• 分子量: 404.375
• InChiKey: FHUXFJUMIZKTKU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  trans-bis(1,2-bis(dimethylphosphino)ethane)(η2-H2)-hydridoruthenium(II)(1+) 、 氘代甲醇 以 氘代甲醇 为溶剂， 生成 trans-[Ru(1,2-bis(dimethylphosphino)ethane)2C(HD)H](1+)
  参考文献：
  名称：

  Aqueous Coordination Chemistry of H₂: Why is Coordinated H₂ Inert to Substitution by Water in trans-Ru(P₂)₂(H₂)H⁺-type Complexes (P₂ = a Chelating Phosphine)?

  摘要：

  The reactivity of a series of trans-Ru(P-2)(2)Cl-2 complexes with H-2 was explored. The complexes reacted with H-2 via a stepwise H-2 addition/heterolysis pathway to form the trans-[Ru(P-2)(2)(H-2)H](+) dihydrogen complexes. Some of the resulting eta(2)-H-2 complexes were surprisingly inert to substitution by water, even at concentrations as high as 55 M; however, the identity of the bidentate phosphine ligand greatly influenced the lability of the coordinated eta(2)-H-2 ligand. With less electron-donating phosphine ligands, the H-2 ligand was susceptible to substitution by H2O, whereas with more electron-rich phosphine ligands, the H-2 ligand was inert to substitution by water. Density functional theory (DFT) calculations of the ligand substitution reactions showed that the Ru-H-2 and Ru-H2O complexes are very close in energy, and therefore slight changes in the donor properties of the bidentate phosphine ligand can inhibit or promote the substitution of H2O for H-2.

  DOI：

  10.1021/ic801884x
• 作为产物：
  描述：

  cis-Ru[(CH₃)2PCH₂CH₂P(CH₃)2]2H₂ 在 ethanol 作用下， 以 乙醇 为溶剂， 生成 trans-bis(1,2-bis(dimethylphosphino)ethane)(η2-H2)-hydridoruthenium(II)(1+)
  参考文献：
  名称：

  Field, Leslie D.; Hambley, Trevor W.; Yau, Benita C. K., Inorganic Chemistry, 1994, vol. 33, # 9, p. 2009 - 2017

  摘要：

  DOI：