(fac-[o-C6H4(PPhCl)(μ2-S)]Mn(CO)3)2 | 161435-86-5

• 英文名称: (fac-[o-C6H4(PPhCl)(μ2-S)]Mn(CO)3)2
• CAS: 161435-86-5
• 化学式: C₃₀H₁₈Cl₂Mn₂O₆P₂S₂
• 分子量: 781.331
• InChiKey: SNQBJUOXFDAXRC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  甲醇 、 (fac-[o-C6H4(PPhCl)(μ2-S)]Mn(CO)3)2 以 甲醇 为溶剂， 以85%的产率得到(fac-[o-C6H4(PPh(OCH3))(μ2-S)]Mn(CO)3)2
  参考文献：
  名称：

  杂化磷和硫供体配体。桥接硫醇复合物

  摘要：

  Reaction of o-C6H4(PPhH)(SH) (3) with Mn(CO)(5)Br and Re(CO)(5)Br in, chloroform provided sulfido-bridged binuclear complexes {fac-[o-C6H4(PPhCl)(mu(2)-S)]Mn(CO)(3)}(2) (4) and [o-C6H4(PPhH)(mu(2)-S)](mu(2)-Br)Re-2(CO)(7) (5), respectively. Both complexes 4 and 5 were characterized by spectral and crystal structural analyses. The hydrogen, atom of the secondary phosphine moiety (P-H) of 3 was replaced by a chlorine atom in dimanganese complex 4 to form P-CI but was retained in rhenium complex 5. Methanolysis of 4 gave methoxyl-substituted product {fac-[o-C6H4(PPh(OCH3))(mu(2)-S)]Mn(CO)(3)}(2).

  DOI：

  10.1021/om00003a067
• 作为产物：
  描述：

  五羰基溴化锰(I) 、 氯仿 、 1-thio-2-(phenylphosphino)benzene 以 氯仿 为溶剂， 以52%的产率得到(fac-[o-C6H4(PPhCl)(μ2-S)]Mn(CO)3)2
  参考文献：
  名称：

  杂化磷和硫供体配体。桥接硫醇复合物

  摘要：

  Reaction of o-C6H4(PPhH)(SH) (3) with Mn(CO)(5)Br and Re(CO)(5)Br in, chloroform provided sulfido-bridged binuclear complexes {fac-[o-C6H4(PPhCl)(mu(2)-S)]Mn(CO)(3)}(2) (4) and [o-C6H4(PPhH)(mu(2)-S)](mu(2)-Br)Re-2(CO)(7) (5), respectively. Both complexes 4 and 5 were characterized by spectral and crystal structural analyses. The hydrogen, atom of the secondary phosphine moiety (P-H) of 3 was replaced by a chlorine atom in dimanganese complex 4 to form P-CI but was retained in rhenium complex 5. Methanolysis of 4 gave methoxyl-substituted product {fac-[o-C6H4(PPh(OCH3))(mu(2)-S)]Mn(CO)(3)}(2).

  DOI：

  10.1021/om00003a067