| 209746-11-2

• CAS: 209746-11-2
• 化学式: C₁₅H₂₃Cl₃Si₂Ti
• 分子量: 413.758
• InChiKey: BZXDHUZSBZEXSU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 水 以 甲苯 为溶剂， 以49%的产率得到
  参考文献：
  名称：

  Silyl and siloxanediyl cyclopentadienyl titanium and zirconium complexes: synthesis and reactivity. X-ray molecular structure of [Zr{η5-C5H4SiMe2(μ-OH)} (μ-Cl)Cl2]2

  摘要：

  Chloro(dimethyl)silyl-eta(5)-cyclopentadienyl group 4 metal complexes of the type [M(mu(5)-C5H4SiMe2 Cl)Cl-3] (M = Ti 1, Zr 2) react with thallium salts Tl(C5H4R) (R = H, SiMe3) to give mixed dicyclopentadienyl derivatives [M(eta(5)-C5H4R)(eta(5)-C5H4SiMe2Cl)Cl-2], (M = Ti, R = H 3, R = SiMe3 4; M = Zr, R = H 5, R = SiMe3 6) in high yield. Hydrolysis of complexes 3 and 4 affords the dinuclear complexes [Ti(eta(5)-C5H4R)Cl-2](2){mu(5)-[(eta(5)-C5H4SiMe2)(2)O]} (R = H 7, R = SiMe3 8) containing a siloxanyl bridge, by elimination of two equivalents of HCl. Reactions of complexes 1 with hydroxo containing reagents such as anhydrous LiOH and SiPh2(OH)(2) give the derivatives [Ti(eta(5)-C5H4SiMe2Cl)Cl-2](2)(mu-O)], 9 and Ti[mu-(mu(5)-C5H4SiMe2OSiPh2-eta(1)-O)]Cl-2, 10 identified by analytical, spectrometric and spectroscopic data. Treatment of analogous complex 2 with water produces the dimeric monocyclopentadienyl zirconium trichloride adduct [Zr(eta(5)-C5H4SiMe2OH)Cl-3](2), 11. Compound 11 has been characterized by X-ray crystallography. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(97)00491-9
• 作为产物：
  描述：

  Ti(η(5)-C5H4SiMe2Cl)Cl3 、 以 甲苯 为溶剂， 以89%的产率得到
  参考文献：
  名称：

  Silyl and siloxanediyl cyclopentadienyl titanium and zirconium complexes: synthesis and reactivity. X-ray molecular structure of [Zr{η5-C5H4SiMe2(μ-OH)} (μ-Cl)Cl2]2

  摘要：

  Chloro(dimethyl)silyl-eta(5)-cyclopentadienyl group 4 metal complexes of the type [M(mu(5)-C5H4SiMe2 Cl)Cl-3] (M = Ti 1, Zr 2) react with thallium salts Tl(C5H4R) (R = H, SiMe3) to give mixed dicyclopentadienyl derivatives [M(eta(5)-C5H4R)(eta(5)-C5H4SiMe2Cl)Cl-2], (M = Ti, R = H 3, R = SiMe3 4; M = Zr, R = H 5, R = SiMe3 6) in high yield. Hydrolysis of complexes 3 and 4 affords the dinuclear complexes [Ti(eta(5)-C5H4R)Cl-2](2){mu(5)-[(eta(5)-C5H4SiMe2)(2)O]} (R = H 7, R = SiMe3 8) containing a siloxanyl bridge, by elimination of two equivalents of HCl. Reactions of complexes 1 with hydroxo containing reagents such as anhydrous LiOH and SiPh2(OH)(2) give the derivatives [Ti(eta(5)-C5H4SiMe2Cl)Cl-2](2)(mu-O)], 9 and Ti[mu-(mu(5)-C5H4SiMe2OSiPh2-eta(1)-O)]Cl-2, 10 identified by analytical, spectrometric and spectroscopic data. Treatment of analogous complex 2 with water produces the dimeric monocyclopentadienyl zirconium trichloride adduct [Zr(eta(5)-C5H4SiMe2OH)Cl-3](2), 11. Compound 11 has been characterized by X-ray crystallography. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(97)00491-9