Al(3-(4-isocyanophenyl)pentane-2,4-dionate)3(AuCl)3 | 1194041-82-1

• 英文名称: Al(3-(4-isocyanophenyl)pentane-2,4-dionate)3(AuCl)3
• 英文别名: Al(acphNCAuCl)3
• CAS: 1194041-82-1
• 化学式: C₃₆H₃₀AlAu₃Cl₃N₃O₆
• 分子量: 1324.89
• InChiKey: HWODLMQSDBTVSH-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  Al(3-(4-formamidophenyl)pentane-2,4-dionate)3 在 POCl₃ 、 NH(CH(CH₃)2)2 作用下， 以 二氯甲烷 为溶剂， 生成 Al(3-(4-isocyanophenyl)pentane-2,4-dionate)3(AuCl)3
  参考文献：
  名称：

  Preparation of an Isocyano-β-diketone via its Metal Complexes, by Use of Metal Ions as Protecting Groups

  摘要：

  A ligand containing isocyanide and beta-diketone functional groups, 3-(4-isocyanophenyl)-2,4-pentanedione (HacphNC), and several of its metal complexes have been prepared. The free isocyano-beta-diketone could not be prepared by dehydration of the analogous formamide, HacphNHCHO, because of the reactivity of its beta-diketone moiety. Instead, the metal complexes Al(acphNC)(3), Fe(acphNC)(3), Cu(acphNC)(2), and Zn(acphNC)(2) were synthesized by dehydration of the. formamido-beta-diketonate complexes Al(acphNHCHO)(3), Fe(acphNHCHO)(3), Cu-(acphNHCHO)(2), and Zn(acphNHCHO)(2). The free isocyano-beta-diketone, HacphNC, can be liberated from its Al and Fe complexes by treatment with oxalate (C2O42-) and HC2O4. In addition to these O-bound complexes, C(N)-bound complexes can be prepared by the reaction of either Al(acphNC)(3) or HacphNC with Au(I). X-ray analyses of HacphNC, Al(acphNC)(3), (HacphNC)AuCl, Cu(acphNHCHO)(2), trans-Zn(acphNHCHO)(2)(H2O)(2), and two other intermediates are also reported.

  DOI：

  10.1021/ic900202e