[Ru(2,2':6,2''-terpyridine)(2,2'-bipyrazine)Cl](1+) | 161302-01-8

• 英文名称: [Ru(2,2':6,2''-terpyridine)(2,2'-bipyrazine)Cl](1+)
• 英文别名: [Ru(2,2',2''-terpyridine)(2,2'-bipyrazine)Cl](1+)
• CAS: 161302-01-8
• 化学式: C₂₃H₁₇ClN₇Ru
• 分子量: 527.958
• InChiKey: QEAKRZDTDXLWJO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ru(2,2':6,2''-terpyridine)(2,2'-bipyrazine)Cl](1+) 、 水 在 silver nitrate 作用下， 以 甲醇 、 水 为溶剂， 生成 [Ru(2,2',2''-terpyridine)(2,2'-bipyrazine)(H2O)](2+)
  参考文献：
  名称：

  One Site is Enough. Catalytic Water Oxidation by [Ru(tpy)(bpm)(OH₂)]²⁺ and [Ru(tpy)(bpz)(OH₂)]²⁺

  摘要：

  Water oxidation is a key reaction in natural photosynthesis and in many schemes for artificial photosynthesis. Although metal complexes capable of oxidizing water based on Ru, Mn, and Ir are known, a significant question is whether or not dimeric or higher order structures are required for water oxidation. We report here single-site catalytic water oxidation by the monomeric complexes [Ru(tpy)(bpm)(OH2)](2+) and [Ru(tpy)(bpz)(OH2)](2+) (tpy is 2,2':6',2 ''-terpyridine; bpm is 2,2'-bipyrimidine; bpz is 2,2'-bipyrazine) by a well-defined mechanism involving Ru-v square O.

  DOI：

  10.1021/ja8059649