| 172374-62-8

• CAS: 172374-62-8
• 化学式: C₂₁H₁₂ClN₆O₃Re
• 分子量: 618.025
• InChiKey: MMVJIPOBELRHJI-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 copper(II) hexafluoroacetylacetonate 以 二氯甲烷 为溶剂， 以60%的产率得到
  参考文献：
  名称：

  Synthesis and characterization of [ReCl(CO)3(L)] [L = 5,6-diphenyl-3-(2-pyridyl)-1,2,4-triazine (dppt) or 3,5,6-tri(2-pyridyl)-1,2,4-triazine (tpt)] and the bidentate coordination of the metalloligand [ReCl(CO)3(tpt)] to [M(hfac)2] (M = Mn, Fe, Co, Ni, Cu, Zn; hfac = hexafluoroacetylacetonate ion)_

  摘要：

  The synthesis and characterization of the novel mononuclear species [ReCl(CO)(3)(L)], where L is 5,6-diphenyl-3-(2-pyridyl)-1,2,4-triazine (dppt) or 3,5,6-tri(2-pyridyl)-1,2,4-triazine (tpt), is reported. The coordination mode of the dppt and tpt ligands to the ReCl(CO)(3) fragment apparently occurs through a pyridyl nitrogen and a triazine nitrogen. In addition, the tpt based monomer [ReCl(CO)(3)(tpt)] behaves as a bidentate metalloligand, reacting with the [M(hfac)(2)] (M = Mn, Fe, Co, Ni, Cu, Zn; hfac = hexafluoroacetylacetonate ion) complexes to produce the heterobimetallic substances [(CO)(3)ClRe(tpt)M(hfac)(2)]. In these Re-tpt-M complexes the tpt-M binding is atypical, since only the two free pyridyl nitrogen atoms of the chelating [ReCl(CO)(3)(tpt)] complex are involved. The new compounds were characterized by IR, H-1 NMR and electronic spectroscopy, electrochemical and magnetic moment measurements.

  DOI：

  10.1016/0277-5387(95)00263-r
• 作为产物：
  描述：

  五羰基氯铼(I) 、 3,5,6-三-2-吡啶基-1,2,4-三嗪 以 甲醇 为溶剂， 以44%的产率得到
  参考文献：
  名称：

  Synthesis and characterization of [ReCl(CO)3(L)] [L = 5,6-diphenyl-3-(2-pyridyl)-1,2,4-triazine (dppt) or 3,5,6-tri(2-pyridyl)-1,2,4-triazine (tpt)] and the bidentate coordination of the metalloligand [ReCl(CO)3(tpt)] to [M(hfac)2] (M = Mn, Fe, Co, Ni, Cu, Zn; hfac = hexafluoroacetylacetonate ion)_

  摘要：

  The synthesis and characterization of the novel mononuclear species [ReCl(CO)(3)(L)], where L is 5,6-diphenyl-3-(2-pyridyl)-1,2,4-triazine (dppt) or 3,5,6-tri(2-pyridyl)-1,2,4-triazine (tpt), is reported. The coordination mode of the dppt and tpt ligands to the ReCl(CO)(3) fragment apparently occurs through a pyridyl nitrogen and a triazine nitrogen. In addition, the tpt based monomer [ReCl(CO)(3)(tpt)] behaves as a bidentate metalloligand, reacting with the [M(hfac)(2)] (M = Mn, Fe, Co, Ni, Cu, Zn; hfac = hexafluoroacetylacetonate ion) complexes to produce the heterobimetallic substances [(CO)(3)ClRe(tpt)M(hfac)(2)]. In these Re-tpt-M complexes the tpt-M binding is atypical, since only the two free pyridyl nitrogen atoms of the chelating [ReCl(CO)(3)(tpt)] complex are involved. The new compounds were characterized by IR, H-1 NMR and electronic spectroscopy, electrochemical and magnetic moment measurements.

  DOI：

  10.1016/0277-5387(95)00263-r