[Pt(Me)(H2O)(2,9-dimethyl-1,10-phenanthroline)(Z-MeO2CCH=CHCO2Me)](1+) | 180396-27-4

• 英文名称: [Pt(Me)(H2O)(2,9-dimethyl-1,10-phenanthroline)(Z-MeO2CCH=CHCO2Me)](1+)
• CAS: 180396-27-4
• 化学式: C₂₁H₂₅N₂O₅Pt
• 分子量: 580.52
• InChiKey: QTXIYWZDDNEWCX-BXRJXUPASA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [Pt(HgMe)(H2O)(2,9-dimethyl-1,10-phenanthroline)(Z-MeO2CCH=CHCO2Me)]BF4 以 硝基甲烷 为溶剂， 生成 [Pt(Me)(H2O)(2,9-dimethyl-1,10-phenanthroline)(Z-MeO2CCH=CHCO2Me)](1+)
  参考文献：
  名称：

  Bi- and trinuclear cationic complexes involving bonds between mercury and five-coordinate platinum(II). Molecular structure of [{Pt(2,9-dimethyl-1,10-phenanthroline)-(Z-MeO2CCH = CHCO2Me)(H2O)}2 Hg](BF4)2

  摘要：

  Three cationic five-coordinate platinum(II) complexes bearing alkylmercury fragments as ''ligands'' have been isolated. The complexes of general formula [Pt(HgR)H2O)dmphen)(ZR' O2CCH=CHCO(2)R')] (BF4) (dmphen=2,9-dimethyl-1,10-phenanthroline; R, R(t)=Me; R=Me, R(t) =(t)Bu; R=(t)Bu, R(t)=Me) are stabilized by the factors operating in related neutral species. Two of the new complexes slowly demercuriatez in solution, affording the mononuclear complexes [Pt(Me)H2O)(dmphen(ZR' O2CCH=CHCO(2)R(t))](BF4) (R(t)=Me or (t)Bu). When R=(t)Bu, a slow redistribution reaction is observed, yielding the trinuclear cluster [{Pt(dmphen)(Z-MeO(2)CCH=CHCO(2)Me)H2O)}Hg-2](BF4)(2). The structure of this complex has been determined by X-ray analysis.

  DOI：

  10.1016/0022-328x(95)05554-3