| 1374643-47-6

• CAS: 1374643-47-6；16071-04-8；67253-11-6
• 化学式: C₁₆H₃₀CoN₆O₄*ClO₄
• 分子量: 528.896
• InChiKey: NSLKTSVXWGSUFU-PRNSBOFBSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  bis(tetrabutylammonium) hexatungstate 、 以 乙腈 为溶剂， 以38%的产率得到
  参考文献：
  名称：

  Inorganic–organic hybrid materials based on Co(III) tetra-aza-macrocyclic complexes and Lindqvist type poly-oxo anions: Synthesis, characterization and spectroscopy of [CoIII(L)(NO2)2]2[Mo6O19] and [CoIII(L)(NCS)2]2[W6O19]·2CH3CN (L=Transdiene)

  摘要：

  This article describes the synthesis and characterization of two polyoxometalate based ion-pair compounds [Co-III(L)(NO2)(2)](2)[Mo6O19] (1) and [Co-III(L)(NCS)(2)](2)[W6O19]center dot 2CH(3)CN (2) (L = 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene). They have been isolated by anionic metathesis of the respective perchlorate and thiocyanate salts with the Lindqvist type isopolyanions. The detailed spectroscopic (IR, UV-visible and ESR) analyses have been performed on compounds 1 and 2 along with their unambiguous crystal structure determination. The polyoxometalate cluster anions not only serve as the counter anions but are also involved in extensive non-covalent interactions with the macrocyclic cationic complexes in their respective crystals. Phase homogeneity of the synthesized compounds in bulk has been established by the X-ray powder diffraction study. Thermal analysis has also been carried out on the title compounds. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2011.07.012
• 作为产物：
  描述：

  、 sodium nitrite 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  Inorganic–organic hybrid materials based on Co(III) tetra-aza-macrocyclic complexes and Lindqvist type poly-oxo anions: Synthesis, characterization and spectroscopy of [CoIII(L)(NO2)2]2[Mo6O19] and [CoIII(L)(NCS)2]2[W6O19]·2CH3CN (L=Transdiene)

  摘要：

  This article describes the synthesis and characterization of two polyoxometalate based ion-pair compounds [Co-III(L)(NO2)(2)](2)[Mo6O19] (1) and [Co-III(L)(NCS)(2)](2)[W6O19]center dot 2CH(3)CN (2) (L = 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene). They have been isolated by anionic metathesis of the respective perchlorate and thiocyanate salts with the Lindqvist type isopolyanions. The detailed spectroscopic (IR, UV-visible and ESR) analyses have been performed on compounds 1 and 2 along with their unambiguous crystal structure determination. The polyoxometalate cluster anions not only serve as the counter anions but are also involved in extensive non-covalent interactions with the macrocyclic cationic complexes in their respective crystals. Phase homogeneity of the synthesized compounds in bulk has been established by the X-ray powder diffraction study. Thermal analysis has also been carried out on the title compounds. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2011.07.012